View More View Less
  • 1 State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, People's Republic of China
  • | 2 Graduate School of Chinese Academy of Sciences, Beijing 100049, People's Republic of China
Restricted access

Abstract

In the current paper, the metal organic coordination polymer Zn4O(OH)2(BDC)2(H2O)2.7 (Zn-MOCP) with high thermal and chemical stability was synthesized by a direct mixing method at room temperature. Then the catalyst Ni@Zn-MOCP (7.5 wt% Ni) was successfully prepared via a wet impregnation strategy employing Ni(acac)2 (acac = acetylacetonate) as the precursor. The hydrogenation of crotonaldehyde was utilized as the probe reaction to explore its catalytic activity. The samples were characterized by powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR), N2 adsorption–desorption measurements, X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). PXRD patterns of Ni@Zn-MOCP showed good coincidence with that of Zn-MOCP, and the pore texture of Zn-MOCP was still maintained after impregnation. Most of Ni(acac)2 over Zn-MOCP were reduced to Ni0 after reduction based on XPS analysis. In terms of the turnover of frequency (TOF) of crotonaldehyde, Ni@Zn-MOCP (53.6 h−1) exhibited much higher activity than the industrial catalyst Ni/SiO2 (29.5 h−1). Furthermore, the reusability of the catalyst Ni@Zn-MOCP over the hydrogenation for crotonaldehyde was tested.

  • 1.

    Chae, HK, Kim, J, Friedrichs, OD, O'Keeffe, M, Yaghi, OM (2003) Angew Chem Int Ed. 42:3907 .

  • 2.

    Dincǎ, M, Yu, AF, Long, JR (2006) J Am Chem Soc. 128:8904 .

  • 3.

    Koh, K, Wong-Foy, AG, Matzger, AJ (2009) J Am Chem Soc. 131:4184 .

  • 4.

    Smaldone, RA, Forgan, RS, Furukawa, H, Gassensmith, JJ, Slawin, AMZ, Yaghi, OM, Stoddart, JF (2010) Angew Chem Int Ed. 49:1.

  • 5.

    Li, HL, Eddaoudi, M, O'Keeffe, M, Yaghi, OM (1999) Nature. 402:276 .

  • 6.

    Huang, LM, Wang, HT, Chen, JX, Wang, ZB, Sun, JY, Zhao, DY, Yan, YS (2003) Microporous Mesopororous Mater. 58:105 .

  • 7.

    Hafizovic, J, Bjørgen, M, Olsbye, U, Dietzel, PDC, Bordiga, S, Prestipino, C, Lamberti, C, Lillerud, KP (2007) J Am Chem Soc. 129:3612 .

  • 8.

    Choi, J, Son, W, Kim, J, Ahn, W (2008) Microporous Mesopororous Mater. 116:727 .

  • 9.

    Biemmi, E, Christian, S, Stock, N, Bein, T (2009) Microporous Mesopororous Mater. 117:111 .

  • 10.

    Eddaoud, M, Kim, J, Rosi, N, Vodak, D, Wachter, J, O'Keeffe, M, Yaghi, OM (2002) Science. 295:469 .

  • 11.

    Rosi, NL, Eckert, J, Eddaoudi, M, Vodak, DT, Kim, J, O'Keeffe, M, Yaghi, OM (2003) Science. 300:1127 .

  • 12.

    Panella, B, Hirscher, M (2005) Adv Mater. 17:538 .

  • 13.

    Dailly, A, Vajo, JJ, Ahn, CC (2006) J Phys Chem B. 110:1099 .

  • 14.

    Wong-Foy, AG, Matzger, AJ, Yaghi, OM (2006) J Am Chem Soc. 128:3494 .

  • 15.

    Li, Y, Yang, RT (2007) Langmuir. 23:12937 .

  • 16.

    Britt, D, Tranchemontagne, D, Yaghi, OM (2008) PNAS. 105:11623 .

  • 17.

    Henschel, A, Gedrich, K, Kraehnert, R, Kaskel, S (2008) Chem Commun. 35:4192 .

  • 18.

    Kleist, W, Jutz, F, Maciejewski, M, Baiker, A (2009) Eur J Inorg Chem. 2009:3552 .

  • 19.

    Tonigold, M, Lu, Y, Bredenkötter, B, Rieger, B, Bahnmüller, S, Hitzbleck, J, Langstein, G, Volkmer, D (2009) Angew Chem Int Ed. 48:1 .

  • 20.

    Hasegawa, S, Horike, S, Matsuda, R, Furukawa, S, Mochizuki, K, Kinoshita, Y, Kitagawa, S (2007) J Am Chem Soc. 129:2607 .

  • 21.

    Müller, M, Hermes, S, Kähler, K MWE van den Berg Muhler, M, Fischer, RA (2008) Chem Mater. 20:4576 .

  • 22.

    Maksimchuk, N, Timofeeva, M, Melgunov, M, Shmakov, A, Chesalov, Y, Dybtsev, D, Fedin, V, Kholdeeva, O (2008) J Catal. 257:315 .

  • 23.

    Tanabe, KK, Cohen, SM (2010) Inorg Chem. 49:6766 .

  • 24.

    Hermes, S, Schröter, M-K, Schmid, R, Khodeir, L, Muhler, M, Tissler, A, Fischer, RW, Fischer, RA (2005) Angew Chem Int Ed. 44:6237 .

  • 25.

    Opelt, S, Türk, S, Dietzsch, E, Henschel, A, Kaskel, S, Klemm, E (2008) Catal Commun. 9:1286 .

  • 26.

    Proch, S, Herrmannsdörfer, J, Kempe, R, Kern, C, Jess, A, Seyfarth, L, Senker, J (2008) Chem Eur J. 14:8204 .

  • 27.

    Greathouse, JA, Allendorf, MD (2006) J Am Chem Soc. 128:10678 .

  • 28.

    Ravon, U, Domine, ME, Gaudillère, C, Desmartin-Chomel, A, Farrusseng, D (2008) New J Chem. 32:937 .

  • 29.

    Farrusseng, D, Aguado, S, Pinel, C (2009) Angew Chem Int Ed. 48:7502 .

  • 30.

    Lee, J, Farha, OK, Roberts, J, Scheidt, KA, Nguyen, ST, Hupp, JT (2009) Chem Soc Rev. 38:1450 .

  • 31.

    Tranchemontagne, DJ, Hunt, JR, Yaghi, OM (2008) Tetrahedron. 64:8553 .

  • 32.

    Dan, Z, Chang, DH, Heng, J, Hong, G (2007) Chem Ind Times. 21:8.

  • 33.

    Rowsell, JLC, Spencer, EC, Eckert, J, Howard, JAK, Yaghi, OM (2005) Science. 309:1350 .

  • 34.

    Rosi, NL, Kim, J, Eddaoudi, M, Chen, B, O'Keeffe, M, Yaghi, OM (2005) J Am Chem Soc. 127:1504 .

  • 35.

    Noller, H, Lin, WM (1984) J Catal. 85:25 .

  • 36.

    Reyes, P, Aguirre, MC, Pecchi, G, Fierro, JLG (2000) J Mol Catal A Chem. 164:245 .