Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 104: Issue 2
Development of a kinetic model of the Fischer–Tropsch synthesis reaction with a cobalt-based catalyst
Authors:
Seung-Ho Kwack Department of Chemical Engineering, Ajou University, Suwon 443-749, Korea

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Myung-June Park Department of Chemical Engineering, Ajou University, Suwon 443-749, Korea

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Jong Wook Bae School of Chemical Engineering, Sungkyunkwan University, Suwon 440-746, Korea

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Kyoung-Su Ha Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology (KRICT), Daejeon 305-600, Korea

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Ki-Won Jun Petroleum Displacement Technology Research Center, Korea Research Institute of Chemical Technology (KRICT), Daejeon 305-600, Korea

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Pages:
483–502
Online Publication Date:
11 Sep 2011
Publication Date:
01 Dec 2011
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-011-0369-1
Keywords:
Cobalt-based catalyst; Fischer–Tropsch synthesis; Kinetics; Parameter estimation; Mathematical modeling
Restricted access

Abstract

A kinetic model of cobalt-based Fischer–Tropsch synthesis was developed through the detailed kinetic study of the reaction mechanism. Experimental evidence and previously reported theoretical analyses were used to suggest the mechanism and derive reaction rates for the formation of hydrocarbon products by applying the equilibrium constants of the adsorbents and the quasi steady state assumption to intermediate species on the surface of the catalyst. The comparison between experimental data and simulated results with kinetic parameters validated the effectiveness of the developed model. Further analysis showed that temperature and H2/CO ratio significantly influenced the entire distribution of hydrocarbon products. The effects of operating conditions were also predicted in accordance with previous work, thus demonstrating that the developed model can contribute to a better understanding of the kinetic mechanism of FT synthesis.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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