Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 105: Issue 1
Catalytic performances of CuGa and CuSn binary oxide catalysts towards N2O decomposition and reduction
Authors:
Antonella Gervasini Dipartimento di Chimica Fisica ed Elettrochimica, Università degli Studi di Milano, via Camillo Golgi n. 19, 20133, Milan, Italy
CIMaINa (Centro Interdisciplinare Materiali e Interfacce Nanostrutturati), Milan, Italy

Search for other papers by Antonella Gervasini in
Current site
Google Scholar
PubMed Close
,
Paolo Carniti Dipartimento di Chimica Fisica ed Elettrochimica, Università degli Studi di Milano, via Camillo Golgi n. 19, 20133, Milan, Italy

Search for other papers by Paolo Carniti in
Current site
Google Scholar
PubMed Close
, and
Simona Bennici Dipartimento di Chimica Fisica ed Elettrochimica, Università degli Studi di Milano, via Camillo Golgi n. 19, 20133, Milan, Italy

Search for other papers by Simona Bennici in
Current site
Google Scholar
PubMed Close
Pages:
53–67
Online Publication Date:
11 Sep 2011
Publication Date:
01 Feb 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-011-0367-3
Keywords:
Nitrous oxide; Catalytic decomposition; Selective catalytic reduction (N2O-SCR); Copper oxide; Gallium oxide; Tin oxide; Binary metal oxides
Restricted access

Abstract

Direct catalytic decomposition of N2O in inert and oxidative atmosphere was investigated over two series of binary oxide catalysts containing CuO coupled with Ga2O3 or SnO2 dispersed over a silica-alumina support (CuGa/SA and CuSn/SA series catalysts). The activity for N2O decomposition in the absence of oxygen was between 0.1 and 0.2 μmol gcat s−1 in the 500–600 °C interval over the CuSn/SA series catalysts with conversion between 80 and 90%. Lower activities with larger differences were observed within the CuGa/SA series catalysts. The presence of oxygen in the feed (O2/N2O ratio up to 20:1) did not affect the activity of the CuGa/SA series while a light decrease of activity could be noticed on the CuSn/SA series. The effect of methane reductant in the selective N2O reduction (N2O-SCR) was tested. On the CuGa/SA series samples, the best reaction selectivity was observed.

  • 1. Centi, G, Perathoner, S, Vazzana, F 1999 Chemtech 29 12 48.

  • 2. Reimer, RA, Slaten, CS, Seapan, M, Lower, MW, Tomlinson, PE 1994 Environ Progr 13:134 .

  • 3. Kapteijn, F, Rodriguez-Mirasol, J, Moulijn, J 1996 Appl Catal B 9:25.

  • 4. Pérez-Ramírez, J 2007 Appl Catal B 70:31 .

  • 5. Kalback, W, Sliepcevich, CM 1978 Ind Eng Chem Fundam 17:165 .

  • 6. Lintz, HG, Riekert, L 1984 J Catal 88:244 .

  • 7. Zeng, HC, Pang, XY 1997 Appl Catal B 13:113 .

  • 8. Centi, G, Dall'Olio, L, Perathoner, S 2000 Appl Catal A 194–195:79.

  • 9. Centi, G, Dall'Olio, L, Perathoner, S 2000 J Catal 194:130 .

  • 10. Boissel, V, Tahir, S, Koh, CA 2006 Appl Catal B 64:234 .

  • 11. Leglise, J, Petunchi, JO, Hall, WK 1984 J Catal 86:392 .

  • 12. Kordulis, C, Latsios, H, Lycourghiotis, A, Promonis, PJ 1990 Chem Soc Faraday Trans 86:185 .

  • 13. Panov, GI, Sobolev, VI, Kharitonov, AS 1990 J Mol Catal 61:85 .

  • 14. Li, Y, Armor, JN 1992 Appl Catal B 1:L21 .

  • 15. Sobolev, VI, Panov, GI, Kharitonov, AS, Romannikov, VN, Volodin, AM, Ione, KG 1993 J Catal 139:435 .

  • 16. Dandekar, A, Vannice, MA 1999 Appl Catal B 22:179 .

  • 17. Nobukawa, T, Yoshida, M, Kameoka, S, Ito, S, Tomishige, K, Kunimori, K 2004 J Phys Chem B 108:4071 .

  • 18. Hansen, N, Heyden, A, Bell, AT, Keil, FJ 2007 J Phys Chem C 111:2092 .

  • 19. Bennici, S, Gervasini, A 2006 Appl Catal B 62:336 .

  • 20. Russo, N, Mescia, D, Fino, D, Saracco, G, Specchia, V 2007 Ind Eng Chem Res 46:4226 .

  • 21. Zhu, ZH, Zhu, HY, Wang, SB, Lu, GQ 2003 Catal Lett 91:73 .

  • 22. Pérez-Ramírez, J, Overeijnder, J, Kapteijn, F, Moulijn, JA 1999 Appl Catal B 23:59 .

  • 23. Alini, S, Basile, F, Blasioli, S, Rinaldi, C, Vaccari, A 2007 Appl Catal B 70:323 .

  • 24. Tuti, S, Pepe, F, Pietrogiacomi, D, Indovina, V 2001 React Kinet Catal Lett 72:35 .

  • 25. Morterra, C, Giamello, E, Cerrato, G, Centi, G, Perathoner, S 1998 J Catal 179:111 .

  • 26. Yao, K-W, Jaenicke, S, Lin, J-Y, Tan, KL 1998 Appl Catal B 16:291 .

  • 27. Liu, Z, Amiridis, MD, Chen, Y 2005 J Phys Chem B 109:1251 .

  • 28. Wang, J, Yasuda, H, Inumaru, K, Misono, M 1995 Bull Chem Soc Jpn 68:1226 .

  • 29. Yasuda, H, Nitadori, T, Mizuno, N, Risono, M 1993 Bull Chem Soc Jpn 66:3492 .

  • 30. Raj, SL, Viswanathan, B, Srinivasan, V 1982 J Catal 75:185 .

  • 31. Hevia, MAG, Pérez-Ramírez, J 2008 Appl Catal B 77:248 .

  • 32. Swamy, CS, Cristopher, J 1992 Catal Rev Sci Eng 34:409 .

  • 33. Winter, ERS 1970 J Catal 19:32 .

  • 34. Ramanujachari, KV, Kameswari, N, Swamy, CS 1984 J Catal 86:121 .

  • 35. Boreskov, GK 1982 JR Anderson M Boudart eds. Catalysis: science and technology 3 Springer-Verlag Berlin 39–137.

  • 36. Cordischi, D, Indovina, V, Occhiuzzi, M, Arieti, A 1979 J Chem Soc Faraday Trans 1 75:533 .

  • 37. Iwamoto, M, Yoda, Y, Yamazoe, N, Seiyama, T 1978 J Phys Chem 82:2564 .

  • 38. Sundarajan, R, Srinivasan, V 1996 Appl Catal A 141:45 .

  • 39. Nobukawa, T, Yoshida, M, Okumura, K, Tomishige, K, Kunimori, K 2005 J Catal 229:374 .

  • 40. Satsuma, A, Maeshima, H, Watanabe, K, Suzuki, K, Hattori, T 2000 Catal Today 63:347 .

  • 41. Kameoka S , Suzuki T, Yuzaki K, Takeda T, Tanaka S, Ito S, Miyadera T, Kunimori K (2000) Chem Commun 745.

  • 42. Yoshida, M, Nobukawa, T, Ito, S, Tomishige, K, Kunimori, K 2004 J Catal 223:454 .

  • 43. Yong, Y, Cant, NW 1990 J Catal 122:22 .

  • 44. Centi, G, Vazzana, F 1999 Catal Today 53:683 .

  • 45. Kameoka, S, Yuzaki, K, Takeda, T, Tanaka, S, Ito, S, Miyadera, T, Kunimori, K 2001 Phys Chem Chem Phys 3:256 .

  • 46. Coq, B, Mauvezin, M, Delahay, G, Kieger, S 2000 J Catal 195:298 .

  • 47. Delahay, G, Mauvezin, M, Coq, B, Kieger, S 2001 J Catal 202:156 .

  • 48. Delahay, G, Mauvezin, M, Guzmán-Vargas, A, Coq, B 2002 Catal Commun 3:385 .

  • 49. Muramatsu, H, Tokura, K, Mori, T, Akahori, R, Watanabe, K, Satsuma, A, Hattori, T, Muratami, Y 1997 Energy Convers Manag 38:1399 .

  • 50. Carniti, P, Gervasini, A, Modica, VH, Ravasio, N 2000 Appl Catal B 28:175 .

  • 51. Kung, MC, Bethke, KA, Lee, J-H, Kung, HH 1997 Appl Surf Sci 121/122:127 .

  • 52. Bennici, S, Auroux, A, Guimon, C, Gervasini, A 2006 Chem Mater 18:3641 .

  • 53. Gervasini, A, Bennici, S, Auroux, A, Guimon, C 2007 Appl Catal A 331:129 .

  • 54. Shelef, M 1995 Chem Rev 95:209 .

  • 55. Bethke, KA, Kung, MC, Yang, B, Shah, M, Alt, D, Li, C, Kung, HH 1995 Catal Today 26:169 .

  • 56. Kung, HH, Kung, MC 1996 Catal Today 30:5 .

  • 57. Márquez-Alvarez, C, Rodríguez-Ramos, I, Guerrero-Ruiz, A, Haller, GL, Fernández-García, M 1997 J Am Chem Soc 119:2905 .

  • 58. Pietrogiacomi, D, Sannino, D, Tuti, S, Ciambelli, P, Indovina, V, Occhiuzzi, M, Pepe, F 1999 Appl Catal B 21:141 .

  • 59. Chen, L, Horiuchi, T, Osaki, T, Mori, T 1999 Appl Catal B 23:259 .

  • 60. Carniti, P, Gervasini, A 2002 Catal Lett 84:235 .

  • 61. Bennici, S, Gervasini, A, Ravasio, N, Zaccheria, F 2003 J Phys Chem B 107:5168 .

  • 62. Bennici, S, Carniti, P, Gervasini, A 2004 Catal Lett 98:187 .

  • 63. Perdigon-Melon, JA, Gervasini, A, Auroux, A 2005 J Catal 234:421 .

  • 64. Park, PW, Ragle, CS, Boyer, CL, Balmer, ML, Enelhard, M, McCready, D 2002 J Catal 210:97 .

  • 65. Gervasini, A, Perdigon-Melon, JA, Guimon, C, Auroux, A 2006 J Phys Chem B 110:240 .

  • 66. Hamada, H, Kintaichi, Y, Yoshinari, T, Tanaba, M, Sasaki, M, Ito, T 1993 Catal Today 17:112 .

  • 67. Subramanian, S, Kudla, RJ, Chun, W, Chattha, MS 1993 Ind Eng Chem Res 32:1805 .

  • 68. Guimon, C, Gervasini, A, Auroux, A 2001 J Phys Chem B 105:10316 .

  • 69. Auroux, A, Sprinceana, D, Gervasini, A 2000 J Catal 195:140 .

  • 70. Gergely, B, Guimon, C, Gervasini, A, Auroux, A 2000 Surf Interface Anal 30:61 .

  • 71. Kung, MC, Park, PW, Kim, D-W, Kung, HH 1999 J Catal 181:1 .

  • 72. Park, PW, Kung, HH, Kim, D-W, Kung, MC 1999 J Catal 184:440 .

  • 73. Teraoka Y , Harada T, Iwasaki T, Ikeda T, Kagawa S (1993) Chem Lett 773.

  • 74. Carniti, P, Gervasini, A, Bennici, S 2005 J Phys Chem B 109:1528 .

  • 75. Gervasini, A, Carniti, P, Ragaini, V 1999 Appl Catal B 22:201 .

  • Collapse
  • Expand
Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

To see the editorial board, please visit the website of Springer Nature.

Manuscript submission: www.editorialmanager.com/reac

For subscription options, please visit the website of Springer Nature.

Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Apr 2024 4 0 0
May 2024 10 0 0
Jun 2024 4 0 0
Jul 2024 9 0 0
Aug 2024 34 0 0
Sep 2024 18 0 0
Oct 2024 6 0 0