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  • 1 Dipartimento di Chimica Fisica ed Elettrochimica, Università degli Studi di Milano, via Camillo Golgi n. 19, 20133, Milan, Italy
  • | 2 CIMaINa (Centro Interdisciplinare Materiali e Interfacce Nanostrutturati), Milan, Italy
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Abstract

Direct catalytic decomposition of N2O in inert and oxidative atmosphere was investigated over two series of binary oxide catalysts containing CuO coupled with Ga2O3 or SnO2 dispersed over a silica-alumina support (CuGa/SA and CuSn/SA series catalysts). The activity for N2O decomposition in the absence of oxygen was between 0.1 and 0.2 μmol gcat s−1 in the 500–600 °C interval over the CuSn/SA series catalysts with conversion between 80 and 90%. Lower activities with larger differences were observed within the CuGa/SA series catalysts. The presence of oxygen in the feed (O2/N2O ratio up to 20:1) did not affect the activity of the CuGa/SA series while a light decrease of activity could be noticed on the CuSn/SA series. The effect of methane reductant in the selective N2O reduction (N2O-SCR) was tested. On the CuGa/SA series samples, the best reaction selectivity was observed.

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  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)