Authors:
Riya Sailani Department of Chemistry, University of Rajasthan, Jaipur 302055, India

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Mridula Sharma Department of Chemistry, University of Rajasthan, Jaipur 302055, India

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Deepmala Pareek Department of Chemistry, University of Rajasthan, Jaipur 302055, India

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C. L. Khandelwal Department of Chemistry, University of Rajasthan, Jaipur 302055, India

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P. D. Sharma Department of Chemistry, University of Rajasthan, Jaipur 302055, India

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Abstract

The kinetics of the oxidation of aspartic acid by peroxomonosulfate catalyzed by ruthenium(III) chloride was studied in acidic medium. The stoichiometry of the reaction corresponds to a reaction in which a mole of the amino acid reacts with a mole of peroxomonosulfate ion. A plausible reaction mechanism has been suggested and the derived rate law accounts for all experimental observations. Activation parameters have also been evaluated.

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
1
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)