Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 105: Issue 2
Synthesis, characterization and hydroformylation catalytic activity of a water-soluble RhCl(CO)(PySO3Na)2 complex using 1-hexene and real naphtha
Authors:
Yuraima Fonseca Facultad de Ciencias Departamento de Química Laboratorio de Organometálicos, Universidad de Los Andes, Mérida 5101, Venezuela

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Bernardo Fontal Facultad de Ciencias Departamento de Química Laboratorio de Organometálicos, Universidad de Los Andes, Mérida 5101, Venezuela

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Marisela Reyes Facultad de Ciencias Departamento de Química Laboratorio de Organometálicos, Universidad de Los Andes, Mérida 5101, Venezuela

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Trino Suárez Facultad de Ciencias Departamento de Química Laboratorio de Organometálicos, Universidad de Los Andes, Mérida 5101, Venezuela

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Fernando Bellandi Facultad de Ciencias Departamento de Química Laboratorio de Organometálicos, Universidad de Los Andes, Mérida 5101, Venezuela

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Juan C. Diaz Facultad de Ciencias Departamento de Química Laboratorio de Organometálicos, Universidad de Los Andes, Mérida 5101, Venezuela

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Pedro Cancines Facultad de Ciencias Departamento de Química Laboratorio de Organometálicos, Universidad de Los Andes, Mérida 5101, Venezuela

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Pages:
307–315
Online Publication Date:
18 Nov 2011
Publication Date:
01 Apr 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-011-0402-4
Keywords:
Hydroformylation; Rhodium complex; Naphtha; Biphasic catalyst
Restricted access

Abstract

In this work, we describe the synthesis and characterization of a new water soluble [RhCl(CO)(PySO3Na)2], complex (1); where [PySO3Na] is the sodium salt of p-sulfonated pyridine ligand. Complex (1) was obtained in methanol, reacting the dried sodium salt of p-sulfonated pyridine ligand with [Rh(Cl)(CO)2]2 complex under inert atmosphere. Complex (1) was characterized by FT-IR and 1H NMR techniques. Complex (1) was active in the catalytic hydroformylation of 1-hexene and real naphtha in a biphasic (water/toluene) system. The effects of reaction time, temperature and syngas pressure were studied with 1-hexene as a substrate. Formation of metallic particles was tested with a mercury drop trial, giving negative results. Reuse of the aqueous phase for several times under the same conditions showed little catalytic activity loss. Complex (1) was active for the hydroformylation reaction of 1-hexene, in the presence of thiophene compounds, showing better performance in comparison with water soluble rhodium analogues.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
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Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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