Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 105: Issue 2
New adsorbents of methanol for the intensification of methanol synthesis
Authors:
L. G. Gordeeva
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A. A. Khassin Boreskov Institute of Catalysis, Ac. Lavrentiev av 5, Novosibirsk 630090, Russia

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G. K. Chermashentseva Boreskov Institute of Catalysis, Ac. Lavrentiev av 5, Novosibirsk 630090, Russia

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T. A. Krieger Boreskov Institute of Catalysis, Ac. Lavrentiev av 5, Novosibirsk 630090, Russia

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Pages:
391–400
Online Publication Date:
07 Oct 2011
Publication Date:
01 Apr 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-011-0379-z
Keywords:
Methanol synthesis; Intensification; Adsorption; Separations; Composites; Salt in porous matrix
Restricted access

Abstract

Novel composite adsorbents Ca(NO3)2)/SiO2, LiBr/SiO2 and CaCl2/SiO2 have been intently designed for shifting the equilibrium of methanol synthesis by methanol removal from the reaction mixture. Testing of these composites in a lab-scale tubular flow reactor at the initial mixture composition CO/CO2/N2/H2 = 30.0/2.0/3.2/64.8, total pressure P = 2 MPa and temperature T = 473 K has shown their encouraging potential for this application. The former composite efficiently adsorbs methanol from the gaseous mixture under lab-scale operating conditions of methanol synthesis and demonstrates good thermal stability. It can be recommended for further testing.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
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Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
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Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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