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  • 1 Boreskov Institute of Catalysis, Ac. Lavrentiev av 5, Novosibirsk 630090, Russia
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Abstract

Novel composite adsorbents Ca(NO3)2)/SiO2, LiBr/SiO2 and CaCl2/SiO2 have been intently designed for shifting the equilibrium of methanol synthesis by methanol removal from the reaction mixture. Testing of these composites in a lab-scale tubular flow reactor at the initial mixture composition CO/CO2/N2/H2 = 30.0/2.0/3.2/64.8, total pressure P = 2 MPa and temperature T = 473 K has shown their encouraging potential for this application. The former composite efficiently adsorbs methanol from the gaseous mixture under lab-scale operating conditions of methanol synthesis and demonstrates good thermal stability. It can be recommended for further testing.

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  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)