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  • 1 College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, People's Republic of China
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Abstract

A carbon-based solid acid catalyst was prepared by incomplete carbonization of H3PO4-impregnated pulp fibers followed by sulfonation. XRD, FT-IR, BET, TGA, and acid density test were employed to characterize the structure and performance of the catalyst. Results showed that the catalyst was amorphous carbon composed of aromatic carbon sheets with –COOH, –OH and –SO3H groups. Previous impregnation with H3PO4 could promote porosity formation of the catalyst. The optimized carbonization temperature and time for the catalyst were 250 °C and 1.5 h. The –SO3H density and specific surface area for the catalyst prepared under the optimized conditions were 1.1 mmol g−1 and 118 m2 g−1, respectively. Compared to HZSM-5, Amberlyst-15 and previous reported carbon catalysts, the catalyst showed higher catalytic activity for transesterification of methyl acetate with n-butanol as hydrophobic reaction. The catalyst had good thermal stability, which could bear 200 °C without decomposition. The catalyst retained satisfactory catalytic activity for transesterification of methyl acetate after 8 reaction cycles.

  • 1. Busca, G 2007 Chem Rev 107:53665410 .

  • 2. Okuhara, T 2002 Chem Rev 102:36413666 .

  • 3. Kozhevnikov, IV 2009 J Mol Catal A: Chem 305:104111 .

  • 4. Okuhara, T, Mizuno, N, Misono, M 2001 Appl Catal A: Gen 222:6377 .

  • 5. Yan, S, DiMaggio, C, Mohan, S, Kim, M, Salley, SO, Ng, KYS 2010 Top Catal 53:721736 .

  • 6. Clark, JH 2002 Acc Chem Res 35:791797 .

  • 7. Horton, B 1999 Nature 400:797799 .

  • 8. Nakajima, K, Hara, M 2007 J Am Ceram Soc 90:37253734.

  • 9. Hara, M, Yoshida, T, Takagaki, A, Takata, T, Kondo, JN, Hayashi, S, Domen, K 2004 Angew Chem Int Ed 43:29552958 .

  • 10. Toda, M, Takagaki, A, Okamura, M, Kondo, JN, Hayashi, S, Domen, K, Hara, M 2005 Nature 438:178 .

  • 11. Suganuma, S, Nakajima, K, Kitano, M, Yamaguchi, D, Kato, H, Hayashi, S, Hara, M 2008 J Am Chem Soc 130:1278712793 .

  • 12. Okamura, M, Takagaki, A, Toda, M, Kondo, JN, Domen, K, Tatsumi, T, Hara, M, Hayashi, S 2006 Chem Mater 18:30393045 .

  • 13. Zong, MH, Duan, ZQ, Lou, WY, Smith, TJ, Wu, H 2007 Green Chem 9:434437 .

  • 14. Mo, X, Lotero, E, Lu, C, Liu, Y, Goodwin, JG 2008 Catal Lett 123:16 .

  • 15. Mirkhani, V, Moghadam, M, Tangestaninejad, S, Mohammadpoor-Baltork, I, Mahdavi, M 2009 Monatsh Chem 140:14891494 .

  • 16. Liang, X, Yang, J 2009 Catal Lett 132:460463 .

  • 17. Xiao, H, Guo, Y, Liang, X, Qi, C 2010 J Solid State Chem 183:17211725 .

  • 18. Xiao, H, Guo, Y, Liang, X, Qi, C 2010 Monatsh Chem 141:929932 .

  • 19. Liang, X, Li, C, Qi, C 2011 J Mater Sci 46:53455349 .

  • 20. Zhang, B, Ren, J, Liu, X, Guo, Y, Guo, Y, Lu, G, Wang, Y 2010 Catal Commun 11:629632 .

  • 21. Rao, BVSK, Chandra Mouli, K, Rambabu, N, Dalai, AK, Prasad, RBN 2011 Catal Commun 14:2026 .

  • 22. Fu, Z, Wan, H, Cui, Q, Xie, J, Tang, Y, Guan, G 2011 Reac Kinet Mech Cat 104:313321 .

  • 23. Suganuma, S, Nakajima, K, Kitano, M, Kato, H, Tamura, A, Kondo, H, Yanagawa, S, Hayashi, S, Hara, M 2011 Micropor Mesopor Mat 143:443450 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 24. Sánchez, JA, Hernández, DL, Moreno, JA, Mondragón, F, Fernández, JJ 2011 Appl Catal A: Gen 405:5560 .

  • 25. Geng, L, Wang, Y, Yu, G, Zhu, Y 2011 Catal Commun 13:2630 .

  • 26. Xing, R, Liu, Y, Wang, Y, Chen, L, Wu, H, Jiang, Y, He, M, Wu, P 2007 Micropor Mesopor Mat 105:4148 .

  • 27. Wang, X, Liu, R, Waje, MM, Chen, Z, Yan, Y, Bozhilov, KN, Feng, P 2007 Chem Mater 19:23952397 .

  • 28. Liu, R, Wang, X, Zhao, X, Feng, P 2008 Carbon 46:16641669 .

  • 29. Nakajima, K, Okamura, M, Kondo, JN, Domen, K, Tatsumi, T, Hayashi, S, Hara, M 2009 Chem Mater 21:186193 .

  • 30. Peng, L, Philippaerts, A, Ke, X, Noyen, JV, Clippel, FD, Tendeloo, GV, Jacobs, PA, Sels, BF 2010 Catal Today 150:140146 .

  • 31. Lin, P, Li, B, Li, J, Wang, H, Bian, X, Wang, X 2011 Catal Lett 141:459466 .

  • 32. Budarin, VL, Clark, JH, Hardy, JJE, Luque, R, Milkowski, K, Tavener, SJ, Wilson, AJ 2006 Angew Chem Int Ed 45:37823786 .

  • 33. Budarin, VL, Clark, JH, Luque, R, Macquarrie, DJ 2007 Chem Commun 6:634636 .

  • 34. Budarin, VL, Clark, JH, Luque, R, Macquarrie, DJ, Koutinas, A, Webb, C 2007 Green Chem 9:992995 .

  • 35. White, RJ, Budarin, VL, Clark, JH 2010 Chem Eur J 16:13261335 .

  • 36. Kitano, M, Arai, K, Kodama, A, Kousaka, T, Nakajima, K, Hayashi, S, Hara, M 2009 Catal Lett 131:242249 .

  • 37. Jagtoyen, M, Thwaites, M, Stencel, J, McEnaney, B, Derbyshire, F 1992 Carbon 30:10891096 .

  • 38. Jagtoyen, M, Derbyshire, F 1993 Carbon 31:11851192 .

  • 39. Sabio, MM, Reinoso, FR, Caturla, F, Sellés, MJ 1995 Carbon 33:11051113 .

  • 40. Solum, MS, Pugmire, RJ, Jagtoyen, M, Derbyshire, F 1995 Carbon 33:12471254 .

  • 41. Teng, H, Yeh, TS, Hsu, LY 1998 Carbon 36:13871395 .

  • 42. Jagtoyen, M, Derbyshire, F 1998 Carbon 36:10851097 .

  • 43. Puziy, AM, Poddubnaya, OI, Alonso, AM, Muñiz, AC, García, FS, Tascón, JMD 2007 Carbon 45:19411950 .

  • 44. Bedia, J, Rosas, JM, Márquez, J, Rodríguez-Mirasol, J, Cordero, T 2009 Carbon 47:286294 .

  • 45. Puziy, AM, Poddubnaya, OI, Kochkin, YN, Vlasenko, NV, Tsyba, MM 2010 Carbon 48:706713 .

  • 46. Bedia, J, Rosas, JM, Vera, D, Rodríguez-Mirasol, J, Cordero, T 2010 Catal Today 158:8996 .

  • 47. Bedia, J, Barrionuevo, R, Rodríguez-Mirasol, J, Cordero, T 2011 Appl Catal B: Environ 103:302310 .

  • 48. Guerrero-Pérez, MO, Rosas, JM, López-Medina, R, Bañares, MA, Rodríguez-Mirasol, J, Cordero, T 2011 Catal Commun 12:989992 .

  • 49. Mo, XH, López, DE, Suwannakarn, K, Liu, YJ, Lotero, E, Goodwin, JG, Lu, CQ 2008 J Catal 254:332338 .