View More View Less
  • 1 Department of Chemistry, Iran University of Science and Technology, Narmak, Tehran, Iran
Restricted access

Abstract

Nanodimensional pores of metal-exchanged zeolite Y containing 5,10,15,20-tetra(4-methoxyphenyl)porphyrin have been prepared by the template “ship-in-a-bottle” method. This approach requires four pyrrole molecules and four 4-methoxy benzaldehyde molecules to diffuse into the pores of FeIII, MnIII and CoIII-exchanged zeolite Y. The host–guest nanocomposite materials have been applied to catalyze the epoxidation of (R)-(+)-limonene, using H2O2/ammonium acetate, at a defined temperature and atmospheric pressure. The encapsulated iron(III) complex is catalytically very efficient as compared to manganese(III) and cobalt(III) complexes for the partial epoxidation of (R)-(+)-limonene and is stable to be recycled without much deterioration. All catalytic systems have been characterized by UV/Vis diffuse reflectance spectroscopic, X-ray diffraction, BET, scanning electron microscopy and energy dispersive X-ray spectrometry analyses to confirm the immobilization of complexes.

  • 1. Kalilur Rahiman, A, Rajesh, K, Shanmuga Bharathi, K, Sreedaran, S, Narayanan, V 2009 J Inorg Chim Acta 362:14911500 .

  • 2. Poltowicz, J, Haber, J 2004 J Mol Catal A Gen 220:4351 .

  • 3. Algarra, F, Esteves, M, Fornes, A, Garc, H Primo 1998 New J Chem 22:333338 .

  • 4. Radha Rani, V, Radha Kishan, M, Kulkarni, SJ, Raghavan, KV 2005 J Catal Commun 6:531538 .

  • 5. Viana Rosa, IL, Manso, CMCP, Serra, OA, Iamamoto, Y 2000 J Mol Catal A Gen 160:199208 .

  • 6. Legrini, E, Oliveros, A, Braun, M 1993 Chem Rev 93:671 .

  • 7. Groves, JT, Nemo, TE, Mayers, RS 1979 J Am Chem Soc 10:1032 .

  • 8. Groves, JT, Kruper, WJ 1980 J Am Chem Soc 102:6375 .

  • 9. Han, AR, Jeong, YJ, Kang, Y, Lee, JY, Seo, MS, Nam, W 2008 Chem Commun 9:1076 .

  • 10. Salavati-Niasari, M 2006 J Inorg Chem Commun 9:628633 .

  • 11. Poltowicz, J, Serwicka, EM, Bastardo-Gonzalez, E, Jones, W, Mokaya, R 2001 J Appl Catal A Gen 218:211217 .

  • 12. Salavati-Niasari, M 2006 J Mol Catal A Chem 245:192199 .

  • 13. Ebadi, A, Nikbakht, F 2011 J Reac Kinet Mech Cat 104:3747 .

  • 14. Ruixin Wang, BG, Jiao, W 2009 J Appl Surf Sci 255:41094113 .

  • 15. Corma, A, Iglesias, M, Mohino, F, Sanchez, F 1997 J Org Chem 544:147156 .

  • 16. Pugin, B 1996 J Mol Catal A 107:273279 .

  • 17. Heinrichs, C, Holderich, WF 1999 J Catal Lett 58:7580 .

  • 18. Kahlen, W, Wagner, HH, Holderich, WF 1998 J Catal Lett 54:8589 .

  • 19. Ogunwumi, SB, Bein, T 1997 J Chem Commun 22:901902 .

  • 20. Sabater MJ , Corma A, Domenech A, Fornes V, Garcia H (1997) J Chem Commun 12851286.

  • 21. Schuster, C, Holderich, WF 2000 J Catal Today 60:193207 .

  • 22. Wan, KT, Davis, ME 1994 J Nature 370:449450 .

  • 23. Benedito, FL, Nakagaki, S, Saczk, AA, Peralta-Zamora, PG, Costa, CMM 2003 J Appl Catal A Gen 250:111 .

  • 24. Karami, D, Rohani, S 2009 J Chem Eng Proc 48:12881292 .

  • 25. Ferchiche S , Warzywoda J, Sacco A Jr (2001) J Inorg Mater 3: 773780.

  • 26. Munoz, R, Beving, D, Mao, Y, Yan, Y 2005 J Microporous Mesoporous Mater 86:243248 .

  • 27. Tan, Q, Bao, X, Song, T, Fan, Y, Shi, G, Shen, B, Liu, C, Gao, X 2007 J Catal 25:6979 .

  • 28. Haber, J, Pamin, K, Poltowicz, J 2004 J Mol Catal A 224:153159 .

  • 29. Salavati-Niasari, M, Davar, F 2006 J Inorg Chem Commun 9:304309 .

  • 30. Skrobot, FC, Rosa, ILV, Marques, APA, Martins, PR, Rocha, J, Valente, AA, Iamamoto, Y 2005 J Mol Catal A Gen 237:8692 .

  • 31. Zhan, BZ, Li, XY 1998 J Chem Commun 67:349350 .

  • 32. Milos, M 2001 J Appl Catal A Gen 216:157161 .

  • 33. Rosa, ILV, Manso, CMCP, Serra, OA, Iamamoto, Y 1999 J Mol Catal A 160:199208.

  • 34. Martins, RRL, Neves, MGPMS, Silvestre, AJD, Simoes, MMQ, Silva, AMS, Tomea, AC, Cavaleiro, JAS, Tagliatesta, P, Crestini, C 2001 J Mol Catal A Chem 172:3342 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 35. Costa, AA, Ghesti, GF JL De Macedo Braga, VS, Santos, MM, Dias, JA, Dias, SCL 2008 J Mol Catal A Chem 282:149157 .

  • 36. Salavati-Niasari, M 2006 J Microporous Mesoporous Mater 92:173180 .

  • 37. Hajimohammadi, M, Bahadoran, F, Hosseiny-Davarani, SS, Safari, N 2010 J Reac Kinet Mech Cat 99:243250.

  • 38. Skrobot, FC, Valente, AA, Nevesa, G, Rosa, I, Rocha, J, Cavaleiro, JAS 2003 J Mol Catal A Gen 201:211222 .

  • 39. Khan, TA, Hriljac, JA 1999 J Inorg Chim Acta 294:179182 .

  • 40. Fei, JH, Tang, XJ, Huo, ZY, Lou, H, Zheng, XM 2006 J Catal Commun 7:827831 .

  • 41. Nakagaki, S, Xavier, CR, Wosniak, AJ, Mangrich, AS, Wypych, F, Cantao, MP, Denicolo, I, Kubotad, LT 2000 J Colloid Surf A Phys Eng Asp 168:261276 .

    • Crossref
    • Search Google Scholar
    • Export Citation
  • 42. Adler, AD, Longo, FR, Finarelli, J 1967 J Goldmach Org Chem 32:476477 .

  • 43. Moghadam, M, Tangestaninejad, S, Mirkhani, V, Mohammadpoor-baltork, I, Sirjanian, N, Parand, S 2009 J Bioorg Med Chem 17:33943398 .

  • 44. Nappa, MJ, Tolman, CA 1985 J Inorg Chem 24:47114719 .

  • 45. Paddock, RL, Hiyama, Y, McKay, JM, Nguyen, SBT 2004 J Tetrahedron Lett 45:20232026 .

  • 46. Zheng, G, Stradiotto, M, Li, L 1998 J Electroanal Chem 453:7988 .

  • 47. Algarra, F, Alexandra Esteves, M, Forne, V, Garc, H, Primo, J 1998 J Chem 22:333338.

  • 48. Casades, I, Constantine, S, Cardin, D, GarcoAa, H, Gilbertb, A, MaArqueza, F 2000 J Tetrahedron 56:69516956 .

  • 49. Liu, C, Yu, W, Li, S, Che, C 1998 J Org Chem 63:73647369 .

  • 50. Chandra, RJ, Varkey, S, Ranasamay, P 1998 J Microporous Mesoporous Mater 22:465474 .

  • 51. Chandra, RJ, Varkey, S, Ranasamay, P 1998 J Appl Catal A Gen 168:353364 .

  • 52. Cooke, PR, Lindsay Smith, JR 1994 J Chem Soc Perkin Trans 1:19131923 .

  • 53. Sercheli, R, Vargas, RM, Sheldon, RA, Schuchardt, U 1999 J Mol Catal A Chem 148:173181 .

  • 54. Balkus, J, Gabrielov, KJ 1995 J Inclusion Phenom Mol Recognit Chem 21:159184.

  • 55. Fan, B, Fan, W, Li, R 2002 J Mol Catal A Chem 201:137145 .

  • 56. Varkey, SP, Ratnasamy, C, Ratnasamy, P 1998 J Mol Catal A Chem 135:295306 .

  • 57. Xavier, KO, Chacko, J, Mohammed Yusuff, KK 2004 J Appl Catal A Gen 258:251259 .

  • 58. Maurya, MR, Titinchi, SJJ, Chand, S, Mishra, IM 2002 J Mol Catal A Chem 180:201209 .

  • 59. Moghadam M , Tangestaninejad Sh, Mirkhani V, Mohammadpoor-Baltork I, Moosavifar M (2009) J Mol Catal A Chem 302: 6875.

Manuscript submission: www.editorialmanager.com/reac

  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

For subscription options, please visit the website of Springer

Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)