Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 107: Issue 1
Photocatalysis of sulfo and carboxy derivatives of indigo in a TiO2 slurry with the use of polychromatic irradiation
Authors:
O. Machalický Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, Studentská 95, 532 10, Pardubice, Czech Republic

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L. Lichý Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, Studentská 95, 532 10, Pardubice, Czech Republic

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M. Tomica Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, Studentská 95, 532 10, Pardubice, Czech Republic

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R. Hrdina Institute of Organic Chemistry and Technology, Faculty of Chemical Technology, University of Pardubice, Studentská 95, 532 10, Pardubice, Czech Republic

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O. Šolcová Institute of Chemical Process Fundamentals of Academy of Sciences of the Czech Republic, Prague, Czech Republic

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Pages:
63–77
Online Publication Date:
05 Apr 2012
Publication Date:
01 Oct 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-012-0442-4
Keywords:
Indigo derivatives; 2-Amino-5-sulfobenzoic acid; Aminoterephthalic acid; Isatine derivatives; Kinetic model of heterogeneous photocatalysis
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Abstract

The photocatalytic decomposition of indigo-5,5′-disulfonic acid (indigocarmine) and indigo-6,6′-dicarboxylic acid has been studied using TiO2 suspension and the polychromatic irradiation of a high-pressure Hg arc lamp. The dyestuffs were dissolved in aqueous medium at pH = 10 and photolyzed in a back-flow tubular photoreactor. The reaction products were determined by HPLC, NMR and MS spectroscopy. Two main photoproducts obtained from indigocarmine (2-amino-5-sulfobenzoic acid and isatine-5-sulfonic acid) were detected. The photocatalysis of indigo-6,6′-dicarboxylic acid gave aminoterephthalic acid and isatine-6-carboxylic acid as two main products. The quantitative analyses of reaction products were performed with UV/Vis and HPLC using chemical standards. A stoichiometric model and kinetic description of photocatalysis of sulfo and carboxy indigo dyes are suggested. The effect of hydroxide and carbonate anions on the rate of photocatalysis was also studied.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
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Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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