Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 107: Issue 2
Application of the Marcus theory to the electron transfer reaction between benzylthioacetic acid and tris(1,10-phenanthroline)iron(III) perchlorate
Authors:
Pathakaraimuthu Balakumar Dr. Sivanthi Aditanar College of Engineering, Tiruchendur 628 215, India

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,
Subramaniam Balakumar PSN College of Engineering and Technology, Tirunelveli 627 152, India

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, and
Perumal Subramaniam Aditanar College of Arts & Science, Tiruchendur 628 216, India

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Pages:
253–261
Online Publication Date:
14 Jul 2012
Publication Date:
01 Dec 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-012-0481-x
Keywords:
Electron transfer reaction; Benzylthioacetic acid; Marcus theory; Tris(1,10-phenanthroline)iron(III) perchlorate
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Abstract

The electron transfer (ET) reaction between benzylthioacetic acid (BTAA) and tris(1,10-phenanthroline)iron(III) perchlorate resulted in the formation of benzylsulfinylacetic acid. The reaction is first order with respect to both BTAA and [Fe(phen)3]3+ and is retarded by hydrogen ion. The ET reaction is studied in 50 % aqueous methanol medium. The Marcus theory is successfully applied to the present redox system and this supports the operation of single electron transfer in the rate controlling step of the reaction.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
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Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
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Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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