Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 107: Issue 2
Highly efficient catalytic dechlorination of organic chlorides with a silica-supported Pd nanoparticle catalyst
Author:
Yuji Ukisu National Institute of Advanced Industrial Science and Technology (AIST), AIST Tsukuba West, 16-1 Onogawa, Tsukuba, Ibaraki, 305-8569, Japan

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Pages:
277–284
Online Publication Date:
14 Aug 2012
Publication Date:
01 Dec 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-012-0489-2
Keywords:
Halogenated organic compounds; Detoxification; Environmental catalyst; Hydrogen transfer reaction
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Abstract

A silica-supported Pd nanoparticle catalyst was prepared by refluxing a Pd(II) precursor in alkaline 2-propanol; it consisted of metallic Pd nanoparticles (ca. 2–8 nm) dispersed in the silica-gel pores. This catalyst exhibited much more efficient dechlorination of p-chloroanisole and 1,1-bis(4-chlorophenyl)-2,2-dichloroethylene (DDE) in an alkaline 2-propanol/methanol (99:1 v/v) solution than a conventional Pd/C catalyst.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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