Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 107: Issue 2
Comparison of the performances of Pt/HBEA nano dispersed over alumina and Pt/ZSM-22 catalysts in n-hexadecane hydroisomerization
Authors:
N. Batalha IC2MP, UMR 7285 CNRS–Université de Poitiers, 4 Rue Michel Brunet, 86022, Poitiers Cedex, France
IBB, Institute for Biotechnology and Bioengineering, Centre for Biological and Chemical Engineering, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal

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L. Pinard IC2MP, UMR 7285 CNRS–Université de Poitiers, 4 Rue Michel Brunet, 86022, Poitiers Cedex, France

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S. Morisset IC2MP, UMR 7285 CNRS–Université de Poitiers, 4 Rue Michel Brunet, 86022, Poitiers Cedex, France

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J. L. Lemberton IC2MP, UMR 7285 CNRS–Université de Poitiers, 4 Rue Michel Brunet, 86022, Poitiers Cedex, France

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Y. Pouilloux IC2MP, UMR 7285 CNRS–Université de Poitiers, 4 Rue Michel Brunet, 86022, Poitiers Cedex, France

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M. Guisnet IC2MP, UMR 7285 CNRS–Université de Poitiers, 4 Rue Michel Brunet, 86022, Poitiers Cedex, France
IBB, Institute for Biotechnology and Bioengineering, Centre for Biological and Chemical Engineering, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal

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F. Lemos IBB, Institute for Biotechnology and Bioengineering, Centre for Biological and Chemical Engineering, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal

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F. R. Ribeiro IBB, Institute for Biotechnology and Bioengineering, Centre for Biological and Chemical Engineering, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001, Lisbon, Portugal

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Pages:
285–294
Online Publication Date:
21 Aug 2012
Publication Date:
01 Dec 2012
Article Category:
Research Article
DOI:
https://doi.org/10.1007/s11144-012-0488-3
Keywords:
Composite materials; BEA nanocrystals; n-C16 hydroisomerization
Restricted access

Abstract

n-Hexadecane hydroisomerization at 220 °C and 30 bar was used as a model reaction for comparing the catalytic performances of a Pt/HBEA sample whose zeolite crystals were germinated on an α alumina surface with those of 1Pt/HZM-22 catalyst well-known for its high isodewaxing selectivity. Similar values of selectivity to isomers were obtained with both catalysts even at high conversions. Moreover, despite its low zeolite content (13 wt%), the Pt/HBEA Al2O3 catalyst had the important advantage to be 4.6 times more active.

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Cover Reaction Kinetics, Mechanisms and Catalysis
Reaction Kinetics, Mechanisms and Catalysis
Print ISSN:
1878-5190
Online ISSN:
1878-5204

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation		 1974
Volumes
per Year		 1
Issues
per Year		 6
Founder Akadémiai Kiadó
Founder's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address		 H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher		 Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)

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