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  • 1 College of Chemical Engineering, Xiangtan University, Xiangtan 411105, China
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Abstract

A new composite catalytic system of Pd/C, 2,4,6-trichloro-[1,3,5]-triazine and N,N-dimethylformamide was investigated in nitrocyclohexane hydrogenation to ∊-caprolactam. The Pd/C catalyst was prepared by the incipient impregnation method and characterized by BET, N2 adsorption–desorption, XRD, TEM and H2 chemisorption. The results indicate that 2,4,6-trichloro-[1,3,5]-triazine plays a key role in one step synthesis of ∊-caprolactam from nitrocyclohexane hydrogenation. Besides ∊-caprolactam, the products include cyclohexanone oxime, cyclohexamine, cyclohexanone and cyclohexanol. A possible mechanism for nitrocyclohexane hydrogenation in 2,4,6-trichloro-[1,3,5]-triazine and N,N-dimethylformamide complex was proposed.

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Manuscript submission: www.editorialmanager.com/reac

  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)