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  • 1 UNICAMP Instituto de Química CP 6154 Campinas SP CEP 13084-862 Brazil
  • | 2 UNICAMP Instituto de Física “Gleb Wataghin” Campinas SP CEP 13083-970 Brazil
  • | 3 Universidade Estadual do Norte Fluminense Laboratório de Ciências Químicas—CCT Av. Alberto Lamego, 2000 Campos dos Goytacazes RJ 28015-620 Brazil
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Abstract  

The activity of solid niobic acid treated with sulfuric acid and with phosphoric acid was tested in the catalytic esterification of oleic acid and in transesterification of soybean oil with methanol. X-ray diffraction studies revealed niobic acid treated with sulfuric acid to be an amorphous solid, while niobic acid treated with phosphoric acid presented a crystalline phase, probably due to the formation of hydrogen niobium phosphate. Among the characterization methods employed here, XPS was particularly instrumental in showing that niobium dihydrogen phosphate and niobium hydrogen sulfate moieties are the acidic active sites responsible for the catalytic effect. The latter is more active according to ammonia TPD studies. Yields as high as 78% in the esterification of oleic acid with methanol and 40% in the transesterification of soybean oil catalyzed by NbSO4 were recorded.

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  • Impact Factor (2019): 1.520
  • Scimago Journal Rank (2019): 0.345
  • SJR Hirsch-Index (2019): 39
  • SJR Quartile Score (2019): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2019): Q4 Catalysis
  • Impact Factor (2018): 1.142
  • Scimago Journal Rank (2018): 0.374
  • SJR Hirsch-Index (2018): 37
  • SJR Quartile Score (2018): Q3 Physical and Theoretical Chemistry
  • SJR Quartile Score (2018): Q3 Catalysis

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Reaction Kinetics, Mechanisms and Catalysis
Language English
Size B5
Year of
Foundation
1974
Volumes
per Year
3
Issues
per Year
6
Founder Akadémiai Kiadó
Founder's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 1878-5190 (Print)
ISSN 1878-5204 (Online)