View More View Less
  • 1 Department of Chemometrics, Institute of Chemistry, Silesian University 9 Szkolna Street, 40-006, Katowice, Poland
  • | 2 Department of Inorganic Chemistry, Faculty of Pharmacy, Medical University in Lublin 6 Staszica Street, 20-081, Lublin, Poland
Restricted access

Summary

In this paper a broad overview of the retention behaviour of twenty flavonoids and their analogues in 74 TLC systems is reported. The compounds were chromatographed on different stationary phases (non-polar and polar-bonded stationary phases — wettable RP18W, silica, and aminopropyl-modified and diol-modified plates) developed with a variety of binary mobile phases (aqueous and non-aqueous). The chemometric techniques principal component analysis and hierarchical clustering were used to evaluate similarities and differences among the chromatographic systems. For selection of the most suitable systems either to perform two-dimensional separation or to enhance overall resolution by merging two stationary phases, indices scoring the separating power of a given system or pair of systems were applied. When separation of all pairs of chromatographic systems was evaluated with the index considered, the theoretical separation achieved in these systems could be visualized as a colour map. This colour map enabled rapid examination of resolution and selection of orthogonal systems enabling acceptable separation of the compounds. On the basis of the colour map it was found that relatively efficient two-dimensional separation of the compounds could be achieved on amino-modified plates developed using 9:1 tetrahydrofuran-water in the first dimension then 9:1, 4:1, 3:1, or 7:3 acetonitrile-water in the second dimension. Theoretically, the best separation could be achieved by combining diol-modified and amino-modified stationary phases and using 3:2 methanol-water and 9:1 acetonitrile-water, respectively, as mobile phases.

  • [1]. E. Van Gyseghem S. Van Hemelryck M. Daszykowski F. Questier D.L. Massart Y. Vander Heyden 2003 J. Chromatogr. A 988 77.

  • [2]. P. Jandera K. Vyňuchalová T. Hájek P. Česla G. Vohralík 2008 J. Chemometrics 22 203.

  • [3]. A. Betti G. Lodi N. Fuzzati 1993 J. Planar Chromatogr. 6 232.

  • [4]. R.E. Mayors 2000 LC-GC Europe 13 232.

  • [5]. R.E. Mayors 2001 LC-GC Europe 14 284.

  • [6]. W. Steuer I. Grant F. Erni 1990 J. Chromatogr. 507 125.

  • [7]. D.W. Speicher 2004 Proteome Analysis Interpreting the Genome Elsevier Amsterdam.

  • [8]. M. Hawrył M. Waksmundzka-Hajnos 2006 J. Planar Chromatogr. 19 92.

  • [9]. M. Hawrył M. Waksmundzka-Hajnos T. Inglot 2005 J. Liq. Chromatogr. Related Technol. 28 2245.

  • [10]. D.R. Stoll X. Lia X. Wang P.W. Carr S.E.G. Porter S.C. Rutan 2007 J. Chromatogr. A 1168 3.

  • [11]. J. Dallüge J. Beens U.A.Th. Brinkman 2003 J. Chromatogr. A 1000 69.

  • [12]. M. Hawrył E. Soczewiński 2000 Chromatographia 52 175.

  • [13]. B.G.M. Vandeginste D.L. Massart L.M.C. Buydens S. de Jong P.J. Lewi J. Smeyers-Verbeke 1998 Handbook of Chemometrics and Qualimetrics, Part B Elsevier Amsterdam.

    • Search Google Scholar
    • Export Citation
  • [14]. M. Daszykowski B. Walczak D.L. Massart 2003 Chemom. Intell. Lab. Syst. 65 97.

  • [15]. M. Daszykowski 2007 J. Chemometrics 21 270.

  • [16]. D.L. Massart L. Kaufman 1989 The Interpretation of Analytical Data by the Use of Cluster Analysis Robert E. Krieger Malabar, Florida.

    • Search Google Scholar
    • Export Citation
  • [17]. N. Bratchell 1987 Chemom. Intell. Lab. Syst. 6 105.

  • [18]. Komsta W. Markowski G. Misztal 2007 J. Planar Chromatogr. 20 27.

The author instruction is available in PDF.
Please, download the file from HERE.
 
The Open Access statement together with the description of the Copyright and License Policy are available in PDF.
Please, download the file from HERE.
 

 

Senior editors

Editor(s)-in-Chief: Kowalska, Teresa

Editor(s)-in-Chief: Sajewicz, Mieczyslaw

Editors(s) Danica Agbaba (University of Belgrade, Belgrade, Serbia);
Ivana Stanimirova-Daszykowska (University of Silesia, Katowice, Poland),
Monika Waksmundzka-Hajnos (Medical University of Lublin, Lublin, Poland)

Editorial Board

R. Bhushan (The Indian Institute of Technology, Roorkee, India)
J. Bojarski (Jagiellonian University, Kraków, Poland)
B. Chankvetadze (State University of Tbilisi, Tbilisi, Georgia)
M. Daszykowski (University of Silesia, Katowice, Poland)
T.H. Dzido (Medical University of Lublin, Lublin, Poland)
A. Felinger (University of Pécs, Pécs, Hungary)
K. Glowniak (Medical University of Lublin, Lublin, Poland)
B. Glód (Siedlce University of Natural Sciences and Humanities, Siedlce, Poland)
K. Kaczmarski (Rzeszow University of Technology, Rzeszów, Poland)
H. Kalász (Semmelweis University, Budapest, Hungary)
I. Klebovich (Semmelweis University, Budapest, Hungary)
A. Koch (Private Pharmacy, Hamburg, Germany)
Ł. Komsta (Medical University of Lublin, Lublin, Poland)
P. Kus (Univerity of Silesia, Katowice, Poland)
D. Mangelings (Free University of Brussels, Brussels, Belgium)
E. Mincsovics (Corvinus University of Budapest, Budapest, Hungary)
G. Morlock (Giessen University, Giessen, Germany)
J. Sherma (Lafayette College, Easton, PA, USA)
R. Skibiński (Medical University of Lublin, Lublin, Poland)
B. Spangenberg (Offenburg University of Applied Sciences, Germany)
T. Tuzimski (Medical University of Lublin, Lublin, Poland)
Y. Vander Heyden (Free University of Brussels, Brussels, Belgium)
A. Voelkel (Poznań University of Technology, Poznań, Poland)
B. Walczak (University of Silesia, Katowice, Poland)
W. Wasiak (Adam Mickiewicz University, Poznań, Poland)

KOWALSKA, TERESA
E-mail: kowalska@us.edu.pl

SAJEWICZ, MIECZYSLAW
E-mail:msajewic@us.edu.pl

Indexing and Abstracting Services:

  • Science Citation Index
  • Sci Search
  • Research Alert
  • Chemistry Citation Index and Current Content/Physical
  • Chemical and Earth Sciences
  • SCOPUS
  • GoogleScholar
  • Index Copernicus
  • CABI
2020
 
Total Cites
650
WoS
Journal
Impact Factor
1,639
Rank by
Chemistry, Analytical 71/83 (Q4)
Impact Factor
 
Impact Factor
1,412
without
Journal Self Cites
5 Year
1,301
Impact Factor
Journal
0,34
Citation Indicator
 
Rank by Journal
Chemistry, Analytical 75/93 (Q4)
Citation Indicator
 
Citable
45
Items
Total
43
Articles
Total
2
Reviews
Scimago
28
H-index
Scimago
0,316
Journal Rank
Scimago
Chemistry (miscellaneous) Q3
Quartile Score
 
Scopus
393/181=2,2
Scite Score
 
Scopus
General Chemistry 215/398 (Q3)
Scite Score Rank
 
Scopus
0,560
SNIP
 
Days from
58
sumbission
 
to acceptance
 
Days from
68
acceptance
 
to publication
 
Acceptance
51%
Rate

2019  
Total Cites
WoS
495
Impact Factor 1,418
Impact Factor
without
Journal Self Cites
1,374
5 Year
Impact Factor
0,936
Immediacy
Index
0,460
Citable
Items
50
Total
Articles
50
Total
Reviews
0
Cited
Half-Life
6,2
Citing
Half-Life
8,3
Eigenfactor
Score
0,00048
Article Influence
Score
0,164
% Articles
in
Citable Items
100,00
Normalized
Eigenfactor
0,05895
Average
IF
Percentile
20,349
Scimago
H-index
26
Scimago
Journal Rank
0,255
Scopus
Scite Score
226/167=1,4
Scopus
Scite Score Rank
Chemistry (miscellaneous) 240/398 (Q3)
Scopus
SNIP
0,494
Acceptance
Rate
41%

 

Acta Chromatographica
Publication Model Online only
Gold Open Access
Submission Fee none
Article Processing Charge 400 EUR/article
Regional discounts on country of the funding agency World Bank Lower-middle-income economies: 50%
World Bank Low-income economies: 100%
Further Discounts Editorial Board / Advisory Board members: 50%
Corresponding authors, affiliated to an EISZ member institution subscribing to the journal package of Akadémiai Kiadó: 100%
Subscription Information Gold Open Access
Purchase per Title  

Acta Chromatographica
Language English
Size A4
Year of
Foundation
1992
Publication
Programme
2021 Volume 33
Volumes
per Year
1
Issues
per Year
4
Founder Institute of Chemistry, University of Silesia
Founder's
Address
PL-40-007 Katowice, Poland, Bankowa 12
Publisher Akadémiai Kiadó
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 0236-6290 (Print)
ISSN 2083-5736 (Online)

Monthly Content Usage

Abstract Views Full Text Views PDF Downloads
Feb 2021 2 0 0
Mar 2021 0 0 0
Apr 2021 5 0 0
May 2021 1 0 0
Jun 2021 6 0 0
Jul 2021 2 1 0
Aug 2021 0 0 0