Multiphase Flow Systems for Selective Aerobic Oxidation of Alcohols Catalyzed by Bimetallic Nanoclusters

Kosuke Kaizuka; Ka-Young Lee; Hiroyuki Miyamura; Shū Kobayashi

doi:10.1556/jfchem.2011.00014

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Journal of Flow Chemistry

Volume/Issue:: Volume 2: Issue 1

Multiphase Flow Systems for Selective Aerobic Oxidation of Alcohols Catalyzed by Bimetallic Nanoclusters

Authors:

Kosuke Kaizuka

Kosuke Kaizuka Department of Chemistry, School of Science, The University of Tokyo, 66-342, Tokyo, Hongo, Bunkyo-ku, Japan

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Ka-Young Lee

Ka-Young Lee Department of Chemistry, School of Science, The University of Tokyo, 66-342, Tokyo, Hongo, Bunkyo-ku, Japan

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Hiroyuki Miyamura

Hiroyuki Miyamura Department of Chemistry, School of Science, The University of Tokyo, 66-342, Tokyo, Hongo, Bunkyo-ku, Japan

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, and

Shū Kobayashi

Shū Kobayashi Department of Chemistry, School of Science, The University of Tokyo, 66-342, Tokyo, Hongo, Bunkyo-ku, Japan

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Pages:: 1–4

Online Publication Date:: 21 Mar 2012

Publication Date:: 21 Mar 2012

Article Category:: Research Article

DOI:: https://doi.org/10.1556/jfchem.2011.00014

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Abstract

Au–Pt and Au–Pd bimetallic nanoclusters that catalyzed the aerobic oxidation of alcohols during a once-through pass through gas–liquid–liquid–solid flow systems were developed. Alcohols were converted to aldehydes and ketones in benzotrifluoride (BTF)/water media by Au–Pt catalyst or to the corresponding methyl esters in methanol/water media by Au–Pd catalyst. The flow systems were superior to the batch systems in terms of both yield and selectivity.

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Journal of Flow Chemistry A Journal of the Flow Chemistry Society

Print ISSN:: 2062-249X

Online ISSN:: 2063-0212

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Journal of Flow Chemistry
Language	English
Size	A4
Year of Foundation	2011
Volumes per Year	1
Issues per Year	4
Founder	Áramlásos Kémiai Tudományos Társaság
Founder's Address	H-1031 Budapest, Hungary Záhony utca 7.
Publisher	Akadémiai Kiadó Springer Nature Switzerland AG
Publisher's Address	H-1117 Budapest, Hungary 1516 Budapest, PO Box 245. CH-6330 Cham, Switzerland Gewerbestrasse 11
Responsible Publisher	Chief Executive Officer, Akadémiai Kiadó
ISSN	2062-249X (Print)
ISSN	2063-0212 (Online)