Authors:
Aiichiro Nagaki Graduate School of Engineering Department of Synthetic Chemistry and Biological Chemistry Kyoto University, Nishikyo-ku Kyoto 615-8510 Japan

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Kana Akahori Graduate School of Engineering Department of Synthetic Chemistry and Biological Chemistry Kyoto University, Nishikyo-ku Kyoto 615-8510 Japan

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Yusuke Takahashi Graduate School of Engineering Department of Synthetic Chemistry and Biological Chemistry Kyoto University, Nishikyo-ku Kyoto 615-8510 Japan

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Jun-ichi Yoshida Graduate School of Engineering Department of Synthetic Chemistry and Biological Chemistry Kyoto University, Nishikyo-ku Kyoto 615-8510 Japan

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Living anionic polymerization of perfluoroalkyl methacrylates initiated by 1,1-diphenylhexyllithium was conducted without adding lithium chloride in an integrated flow microreactor system. The high degree of polydispersity index (PID) control was achieved at 0 °C (2-(nonafluorobutyl)ethyl and 2-(tridecafluorohexyl)ethyl methacrylates) or −40 °C (2,2,2-trifluoroethyl methacrylate). The subsequent reaction of a reactive polymer chain end with alkyl methacrylates or tert-butyl acrylate led to the formation of fluorine-containing block copolymers with narrow PDI.

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Journal of Flow Chemistry
Language English
Size A4
Year of
Foundation
2011
Volumes
per Year
1
Issues
per Year
4
Founder Áramlásos Kémiai Tudományos Társaság
Founder's
Address
H-1031 Budapest, Hungary Záhony utca 7.
Publisher Akadémiai Kiadó
Springer Nature Switzerland AG
Publisher's
Address
H-1117 Budapest, Hungary 1516 Budapest, PO Box 245.
CH-6330 Cham, Switzerland Gewerbestrasse 11
Responsible
Publisher
Chief Executive Officer, Akadémiai Kiadó
ISSN 2062-249X (Print)
ISSN 2063-0212 (Online)