Plain and N-doped carbonaceous particles are synthesized from biomass resources such as glucose via continuous hydrothermal carbonization (HTC) process at 200 °C and 250 psi for the first time using a microfluidic system in a fast and continuous manner. The continuous HTC is controlled by reaction time (3.7–30 min) and concentration (0–10 wt.%) of ethylenediamine as a nitrogen additive to produce a series of the plain carbonaceous and N-doped carbonaceous particles with size range from 0.8 to 1.2 um. The as-synthesized and the pyrolyzed particles are characterized by various analytical instruments to understand their chemical structures with elemental compositions, morphology of particles, and thermal defunctionalization.
Xie, Z.-L.; White, R. J.; Weber, J.; Taubert, A.; Titirici, M. M. J. Mater. Chem. 2011, 20, 7434.
Liang, C.; Li, Z.; Dai, S. Angew. Chem., Int. Ed. 2008, 20, 3696.
Titirici, M.-M.; Thomas, A.; Antonietti, M. New J. Chem. 2007, 6, 787.
Sun, X.; Li, Y. Angew. Chem., Int. Ed. 2004, 5, 597.
Li, M.; Li, W.; Liu, S. X. Carbohydr. Res. 2011, 8, 999.
Lin, X. Z.; Terepka, A. D.; Yang, H. Nano Lett. 2004, 11, 2227.
King’ondu, C. K.; Opembe, N. N.; Genuino, H. C.; Garces, H. F.; Njagi, E. C.; Iyer, A.; Huang, H.; Dharmarathna, S.; Suib, S. L. J. Phys. Chem. C2011, 47, 23273.
Hoang, P. H.; Park, H.; Kim, D.-P. J. Am. Chem. Soc. 2011, 37, 14765.
Marre, S.; Park, J.; Rempel, J.; Guan, J.; Bawendi, M. G.; Jensen, K. F. Adv. Mater. 2008, 24, 4830.
Lu, Y.; Zhang, L.; Lin, H. Chem. - Eur. J. 2014, 15, 4246.
Shen, W.; Fan, W. J. Mater. Chem. A2013, 4, 999.
Zhu, S. J.; Meng, Q. N.; Wang, L.; Zhang, J. H.; Song, Y. B.; Jin, H.; Zhang, K.; Sun, H. C.; Wang, H. Y.; Yang, B. Angew. Chem., Int. Ed. 2013, 14, 3953.
Sevilla, M.; Fuertes, A. B. Chem. - Eur. J. 2009, 16, 4195.
Mohiuddin Mala, G.; Li, D.; Dale, J. D. Int. J. Heat Mass Transfer1997, 13, 3079.
Zhang, L.; Wang, Y.; Tong, L. M.; Xia, Y. N. Langmuir2013, 50, 15719.
White, R. J.; Yoshizawa, N.; Antonietti, M.; Titirici, M. M. Green Chem. 2011, 9, 2428.
Baccile, N.; Laurent, G.; Coelho, C.; Babonneau, F.; Zhao, L.; Titirici, M. M. J. Phys. Chem. C2011, 18, 8976.
Demir-Cakan, R.; Baccile, N.; Antonietti, M.; Titirici, M. M. Chem. Mater. 2009, 3, 484.
Sun, L.; Wang, L.; Tian, C.; Tan, T.; Xie, Y.; Shi, K.; Li, M.; Fu, H. RSC Adv. 2012, 10, 4498.
Zhao, L.; Baccile, N.; Gross, S.; Zhang, Y.; Wei, W.; Sun, Y.; Antonietti, M.; Titirici, M.-M. Carbon2010, 13, 3778.
Singh, A. K.; Basavaraju, K. C.; Sharma, S.; Jang, S.; Park, C. P.; Kim, D.-P. Green Chem. 2014, 30, 3024.