The sol gel method was used in preparing a series of A site partially substituted La1−xBaxCoO3 (x ≥ 0.1 ≤ 0.4) perovskite catalysts coded LBC1, 2, 3, and 4 and their potential as catalysts for soot oxidation were evaluated. The Brunauer–Emmett–Teller (BET), Inductively Coupled Plasma Atomic Emission Spectroscopy (ICPAES), Thermogravimetric/Differential Thermal Analysis (TGA/DTG), X-ray analysis (XRD) were used in characterizing the prepared perovskite catalyst. The result shows that at (x≥ 0.2 ≤ 0.4), there was an increase in surface area when we compare it with that of x = 0. The increase in surface area helps in increasing the catalytic performance of the catalyst. Also, when evaluating the catalytic performance of the synthesized catalysts, it was observed that doping the perovskite catalysts helped in the general improvement of the catalytic performance for soot oxidation. The best performance in this research study with a T50 of 484 °C was observed at x = 0.2 catalyst (LBC2). This shows that the non-noble perovskite catalysts prepared in this research study has the potential to replace the noble metal based catalysts used presently in the diesel automotive industry.
Authors:G. Lizia Thankam and Neelakantan Thurvas Renganathan
Though being an ancient trend, usage of the homogeneous material cement in the construction industry is steadily getting eradicated with the springing up of supplementary cementing materials (SCM). Metakaolin is an imminent mineral admixture extracted from the mineral ore kaolinite, which enhances the interfacial zone by more efficient packing at the cement paste-aggregate particle interface, thus reducing the bleeding and producing a denser, more homogeneous transition zone microstructure. This paper depicts the various repercussions of the pozzolanic material metakaolin in the fresh and hardened properties of concrete when replaced with cement in finite amount. Also, it states the behavior of high-performance concrete and self-compacting concrete with metakaolin.
The inelastic buckling behaviour of different rectangular thin isotropic plates having a free edge is studied. Various combinations of boundary conditions are subject to in-plane uniaxial compression and each rectangular plate is bounded by an unloaded free edge. The characteristic deflection function of each plate is formulated using a polynomial function in form of Taylor–Maclaurin series. A deformation plasticity approach is adopted and the buckling load equation is modified using a work principle technique. Buckling coefficients of the plates are calculated for various aspect ratios and moduli ratios. Findings obtained from the investigation are found to reasonably agree with data published in the literature.
Industry 4.0 is referred as the fourth industrial revolution that represents the information intensive transformation of industrial automation and manufacturing processes. Cyber-physical systems (CPS) are building blocks in Industry 4.0 and part of the Industry 4.0 vision. This paper presents a cyber-physical platform development and implementation strategy for Industry 4.0 applications. It has been considered a cyber-physical platform model (CPP) built upon hardware reconfigurable technology based on a Field Programmable Gate Array (FPGA) processor framework. The development strategy exploits the full benefits enabled by reconfigurable hardware, such as scalability of complex systems, platform-based design approach, adaptive processing, real-time constrains management, or high performance prototyping capabilities. The implemented experimental setup also combines major advantages of both the hardware and software platform-based design trends in Industry 4.0. In this endeavor, the used software toolkit comprises the entire system complexity as a high performance integration layer. The presented design method and implementation strategy can serve as rough orientation for future CPS research and development activities.
Reliability is one of the most important criteria that characterize last generation digital systems. In a wide range of applications the required reliability level is achieved by using hardware redundant configurations. Perhaps their most common form is the triple modular redundancy (TMR) based on a majority voting structure. Researchers that use this strategy make a major assumption: in fault-free operation mode the outputs of these digital systems match in all. This paper proves that synchronization and matching in all the outputs of such systems is not such a trivial problem. In this endeavor FPGA-based (Field Programmable Gate Arrays) redundant topologies are considered for study and experiments. Upon these structures specially conceived redundant models have been developed and simulated. The results outline that synchronization of complex digital systems is a difficult engineering undertaking and any initial assumption should be managed with the adequate circumspection.
Authors:Sommai Khantong, Mohammad Nazir Ahmad Sharif, and Ahmad Kamil Mahmood
Information management and sharing is an essential ingredient, but a difficult and challenging problem for disaster response management. This paper proposes an ontology as a model to organize and structure information in order to improve the information management and sharing in disaster response management. The ontology was designed and developed based on philosophically grounded foundational ontologies. It was also implemented in ontological languages and demonstrated and evaluated in a case study of the flood evacuation process. This paper also provides a systematic approach to develop a well-founded domain ontology that addresses both static and dynamic aspects of a given domain.
Authors:F. Khalfallah, Z. Boumerzoug, S. Rajakumar, and E. Raouache
The objective of this work is to investigate the rotary friction welding of AA1100 aluminum alloy with mild steel, and to optimize the welding parameters of these dissimilar materials, such as friction pressure/time, forging pressure/time and rotational speed. The optimization of the welding parameters was deduced by applying Response Surface Methodology (RSM). An empirical relationship was also applied to predict the welding parameters. Tensile test and micro-hardness measurements were used to determine the mechanical properties of the welded joints. Some joints were analyzed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) in order to investigate the formation of intermetallic compound (IMC) layer at the weld interface. Experimentally, the tensile strength of the weld increases with increasing the forging pressure/time, while the low level of forging pressure/time allows the formation of an IMC layer which reduces the tensile strength of the weld.
The use of energy in the world today is increasing with increase in population. The cost and availability of energy significantly impacts our quality of life, the health of national economies and the stability of our environment. The rapid depletion of fossil fuel resources on a worldwide basis has necessitated an urgent search for alternative energy sources to cater to the present day demands. In recent years there has been a significant global commitment to develop clean and alternative sources of energy such as solar and wind. Wind energy technology has been the fastest growing energy source because it is fairly distributed around the world and readily available for use. However, more penetration of wind energy into existing power networks has some impacts on the stability of the power system. Therefore, this paper studies and analyzes the stability of a power system with increasing wind penetration. The paper presents some analyses of a power system and the dynamic behavior which identify the issues that limit the large-scale integration of wind generators in a power system.
Frequency Hopping Spread Spectrum (FHSS) communications utilizes a pseudo random code to spread the bandwidth of the data being transmitted over a much wider range than is required by the data. Due to the pseudo random nature of the carriers selected for transmission, the spreading and dispreading process must occur simultaneously to recover the transmitted data signal. This requires the receiver have knowledge about the instant the transmitter began transmitting and the propagation delay between the two. However, in real world systems, this information is unavailable to the receiver. The paper utilizes MATLAB Simulink to demonstrate a method of synchronizing the code clock at the receiver with the code clock at the transmitter. This fine alignment process is known as code tracking.
Authors:Wisdom Okechukwu Egbujuo, Placid Ikechukwu Anyanwu, and Henry Chinedu Obasi
Natural rubber (NR) vulcanizates were prepared from natural rubber and chitin using a two-roll mill. The chitin was extracted from crab shell waste obtained from a local market in Oron, Akwa Ibom State, Nigeria using the chemical extraction method. The effects of the chitin at different contents (0–40 phr) on the mechanical properties of the NR/Chitin vulcanizates with carbon black as reference filler have been investigated. The tensile strength of the chitin filled natural rubber (NCH), and the carbon black filled natural rubber (NCB) vulcanizates were found to increase with an increase in filler content to reach optimum at 30 phr after which it decreased. The hardness, impact and abrasion resistance properties of the NCH and NCB vulcanizates increased as filler content increases. The tensile strength and abrasion resistance of the vulcanizates containing blends of varying percentages of carbon black to chitin (CBCH) increased as more carbon black (CB) is introduced while the hardness and impact strength increased with increase in chitin content. However, carbon black filled vulcanizates showed better property enhancement than the chitin filler.