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The solid-state ion-exchange procedures of zeolites with Cu2+, Ni2+, Fe2+ and Co2+ salts can be resulted in prosperous catalysts for NO decomposition. Reactions taking place in solid-state between four transition metal cholirides and H-ZS-5 zeolite were investigated by means of a derivatograph. The results showed that irreversible consumption of surface -OH groups occurred with simultaneous bonding of the transition metal in the zeolite channel structure.

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Journal of Thermal Analysis and Calorimetry
Authors: Á. Fudala, I. Kiricsi, S.-I. Niwa, M. Toba, Y. Kiyozumi, and F. Mizukami
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Abstract  

Mg-Al L(ayered) D(ouble) H(ydroxide) was prepared and its thermal behaviour was characterized by thermoanalytical methods (TG, DTG, DTA), 27Al M(agic) A(ngle) S(pinning) NMR spectroscopy, X-ray diffractometry (XRD) and S(canning) E(lectron) M(icroscopy). Heat treatment destroyed the layered structure, which could only be partially reconstituted by rehydration. On calcination mixed oxide with the predominance of basic sites were formed. Pillaring the LDH with Fe(CN)6 4- anions was also performed. The material was characterized by XRD and BET measurements. Heat stability of the pillared substance was investigated, too. Pillaring proved to be successful, however, decreased heat resistance was found in the intercalated material relative to the guest LDH.

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