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Journal of Radioanalytical and Nuclear Chemistry
Authors:
E. Antonova
,
T. Troshchilova
, and
O. Povolotskaya
Abstract
Radiolysis of binary mixtures isooctance-benzene and isooctane-hexafluorobenzene has been studied. The yields of light products of isooctane radiolysis, namely, G/H2/, G/CH4/, G/C4H10/ and G/C4H8/, have been determined for various electron ratios of benzene- and hexafluorobenzene. The acceptance of positive charges with benzene and of electrons with hexafluorobenzene is reponsible for deviations of radiation-chemical yields towards negative side from the additivity rule. Positive deviation of G/CH4/, G/C4H10/ and G/C4H8/ yields at
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$$\varepsilon _{C_6 F_6 } > 0.9$$
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is attributed to indirect ionization of isooctane. Monomolecular reactions of C8H
18
+
have been discussed.
