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Abstract  

An intercomparison exercise has been carried out on the measurement of237Np in a sample of sea-born sediment taken from the estuary of the River Esk in Cumbria, United Kingdom. The sediment had been contaminated by radioactive liquid discharges from the nuclear fuels reprocessing plant at Sellafield. The measure of agreement between the submitted values was such that one would accept with confidence237Np analyses reported by the participating laboratories. The exercise was arranged by the Analysts' Informal Working Group (AIWG). The AIWG is a small group of chemists from several Government laboratories in the United Kingdom having an interest in radionuclides in the environment. From time-to-time the Group arranges intercomparison exercises; these exercises are in addition to the members' normal quality assurance schemes, and in addition to intercomparison exercises arranged by other organizations. So far as the authors are aware, there has been no report of such an exercise involving237Np, and there appear to be no natural matrix reference materials available for environmental237Np.

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Abstract  

Improvements in analytical methodology for the determination of210Pb and210Po in environmental materials have been the subject of continuing study. Early work showed that the most time-consuming part of the analysis was the wet ashing stage. Investigations have now been carried out to improve this part of the analytical scheme. This paper describes a modified method that has been developed and tested and which has been in routine use for about one year. The time required for the analysis has been reduced and the spectral quality of the sources has been improved. Test samples gave chemical recoveries that were higher, but this improvement has not yet been observed in operational work. Some analytical schemes in which210Pb and210Po are to be determined in the same sample require the addition of stable lead carrier. In some cases, this can lead to the addition of significant quantities of210Po. The results of an investigation of the210Po content of various lead carriers are described and the implications of their use on the determination of210Po in environmental materials are discussed.

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Abstract  

The Standard Reference Material 4351 from the National Institute of Standards and Technology is acknowledged to be inhomogeneous. The value of a single analysis for239Pu+240Pu could lie within a wide range, but the accuracy of the analysis can be corroborated by comparing the corresponding238Pu/239Pu+240Pu or240Pu/239Pu values with the relationships between these ratios and the total plutonium concentration.

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Journal of Radioanalytical and Nuclear Chemistry
Authors:
M. Pham
,
M. Betti
,
P. Povinec
,
M. Benmansour
,
R. Bojanowski
,
P. Bouisset
,
E. Calvo
,
G. Ham
,
E. Holm
,
M. Hult
,
C. Ilchmann
,
M. Kloster
,
G. Kanisch
,
M. Köhler
,
J. La Rosa
,
F. Legarda
,
M. Llauradó
,
A. Nourredine
,
J.-S. Oh
,
M. Pellicciari
,
U. Rieth
,
A. Rodriguez y Baena
,
J. Sanchez-Cabeza
,
H. Satake
,
J. Schikowski
,
M. Takeishi
,
H. Thébault
, and
Z. Varga

Abstract  

A new Reference Material (RM) for radionuclides in mussel (Mytilus galloprovincialis) from the Mediterranean Sea (IAEA-437) is described and the results of the certification process are presented. Four radionuclides (40K, 234U, 238U, and 239+240Pu) have been certified, and information values on massic activities with 95% confidence intervals are given for nine radionuclides (137Cs, 210Pb(210Po), 226Ra, 228Ra, 228Th, 230Th, 232Th, 235U, and 241Am). Results for less frequently reported radionuclides (90Sr, 129I, 238Pu, 239Pu, and 240Pu) are also reported. The RM can be used for quality assurance/quality control of the analysis of radionuclides in mussel samples, for the development and validation of analytical methods and for training purposes. The material is available in 200 g units.

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