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Enthalpy of formation of lithium hexafluorophosphate was calculated based on the differential scanning calorimetry study of heat capacity and thermal decomposition. It was found that thermal decomposition of LiPF6 proceeds at normal pressure in the temperature range 450-550 K. Enthalpy of LiPF6 decomposition is Δd H(LiPF6, c, 298.15 K)= 84.271.34 kJ mole-1. Enthalpy of formation of lithium hexafluorophosphate from elements in standard state is Δf H 0(LiPF6,c, 298.15 K) = -22963 kJ mol-1.

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DSC and vapour pressure measurements are presented on some Be, Al and Cr complexes with 2,4-pentanedione tetramethyl-3,5-heptanedione, 1,1,1-trifluoro-2,4-pentanedione and hexafluoro-2,4-pentanedione. Thermodynamic functions are given for the sublimation, vaporization and melting processes of the substances.

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Journal of Thermal Analysis and Calorimetry
Authors: G. A. Sharpataya, K. S. Gavrichev, A. V. Khoroshilov, V. N. Plakhotnik, and V. M. Gurevich

The heat capacity of cesium hexafluoroarsenate, CsAsF6, was measured from 300 to 850 K by differential scanning calorimetry. The results indicate that the structural transformation from the rhombohedral to cubic phase, occurring in the range 235-360 K, relates to gradual transition completed isothermally. The enthalpy of the transition is 6.015±0.186 kJ mol-1, and its entropy is 17.21±0.58 J K-1 mol-1Rln8, which suggests that this structural transition belongs to the order-disorder type. The thermodynamic properties of CsAsF6 were evaluated in the range 10-760 K.

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