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On the example of the non-isothermal decomposition of pyridine complexes of Co(II)Clunder high-vacuum conditions, a method is demonstrated for determining kinetic parameters without assumptions concerning the dependence of the rate of reaction on the concentration. There are significant differences between decomposition under high-vacuum and atmospheric conditions. Experimental results can be described quantitatively assuming a rate-controlling desorption of surface-bound pyridine molecules in equilibrium with molecules in the interior of the crystallites.

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Kinetische Analyse von komplexen Desorptionsreaktionen

II. Messung Kinetischer Grössen Durch Fraktionierte Thermodesorption

Journal of Thermal Analysis and Calorimetry
Authors: J. Kirchhof and H. Hobert
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