Search Results

You are looking at 1 - 1 of 1 items for :

  • Author or Editor: Miloslav Pekař x
  • Chemistry and Chemical Engineering x
  • Refine by Access: All Content x
Clear All Modify Search


Using several reaction examples with experimentally determined rate equations, traditional mass-action rate equations are shown to be simplified forms of polynomial approximation to a general rate function derived by non-equilibrium thermodynamics for a mixture of fluids with linear transport properties. The mass-action kinetic law is thus proved also on the macroscopic level and limited to this type of fluids.

Restricted access