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The forms and stocks of secondary carbonate accumulations and the distribution of secondary carbonate content were investigated in 20 soil profiles from Nagy-hegy, Tokaj. The secondary carbonate content varied to a great extent under different lithological conditions. The frequency of carbonate crusts coating the coarse fragments to a thickness of 1–7 mm was especially conspicuous. In selected profiles the amount of secondary carbonates was analysed separately for three carbonate pools: in the fine earth (<2 mm), in carbonate crusts and other concentrations, and in the skeletal part of the soils (dominantly dacite blocks and boulders). In one profile a calculation was made of the calcium carbonate stocks (in kg m−2) in the separate fractions of the fine earth, the skeletal fraction and the carbonate crusts and concentrations. The values obtained for the distinct soil horizons were then summed for the whole profile above the continuous hard rock.
The loess deposits can be regarded as the primary source of calcium carbonate, but many types of secondary carbonate accumulations occurred in places where the loess deposits were completely eroded or the original surface of the soil was only preserved on terraces with retaining walls. The results suggest that the highest accumulation of calcium carbonate occurs in profiles where loess, redeposited loess or colluvial deposit covers weathered volcanic rocks (pyroxene dacite), resulting in lithological discontinuity.
The carbonate crusts consisted of 55–96 % (m/m) CaCO3, and the coarse fraction (dacite boulders and blocks) also had a higher calcium carbonate content (5–10 % m/m) than the non-weathered pyroxene dacite. The calcium carbonate stocks in Calcic accumulation horizons proved to be 2.5 times higher than in the overlying soil horizons.
The accumulation forms of carbonates in the soil profiles and the lack of loess deposits on the top of the soil profiles suggest that the calcium carbonate was accumulated in the transitional zone between the loess and the weathered volcanic rocks. This appears to have taken place under humid climatic conditions, unlike the recent climate, and can thus be regarded at least partially as the result of paleoecological processes.
Abstract
The investigation of the effect of petrography and diagenetic features on the geomechanical properties of the sandstone and their relationship to rock failure are of vital importance for different construction projects. The present study involves analyzing multi-vertical lithofacies profiles around the region of Wadi Halfa, North Sudan. The sandstone is dominantly composed of monocrystalline quartz grains (60%) accompanied by some polycrystalline quartz, feldspars, lithic fragments, micas, and heavy minerals. Iron oxides are the main type of cementing materials (14%), with some (2%) of carbonates and clay minerals. The average porosity of all studied samples is 12%. The compressive strength ranges widely, influenced by weathering, grain size, cementing materials, and bedding planes. The uniaxial compressive strength is more influenced by wetting when the load is parallel to bedding planes. Sandstone anisotropy is suggested by a U-shaped curve, with lower values at 45° and higher values at 90° and 0°. The geomechanical behavior of rocks masses in Wadi Halfa was evaluated through a combination of field and laboratory analyses which revealed a variable Rock Mass Rating (RMR) ranging from 58 to 92 and a Geological Strength Index (GSI) ranging from 33 to 61.
