In order to study the thermal properties of new type environment-friendly binary hydrate for cold storage in air-conditioning
system, tests have been carried out by DSC comprehensively on the phase-change temperature and fusion heat of TBAB hydrate,
THF hydrate, and TBAB–THF hydrate mixture. The results show a good trend that TBAB–THF hydrate has the superiority for more
proper phase-change temperature and increased fusion heat. A broader and more developed view is that adding appropriate amount
of hydrate with lower phase-change temperature to hydrate with higher one can make the hydrate mixture more suitable for cold
storage (especially for 278–281 K); some hydrates with lower phase-change temperature can even make the fusion heat of mixture
hydrate increased greatly. Several new environmental working pairs for binary gas hydrates have been listed to help to promote
Authors:Przemysław Rybiński, Grażyna Janowska, and Ludomir Ślusarski
The article presents the results of testing thermal properties and combustibility of butadieneacrylonitrile
rubber with 18% contents of bounded acrylonitrile, NBR 18. Two types of silica, Zeosil 175C and Ultrasil VN-3, with different
specific surfaces were used as filler.
Zeosil 175C and Ultrasil VN-3 were modified via cryogenic dezaggregation method. The activity of
unmodified and cryogenic modified silica toward butadiene-acrylonitrile rubber were investigated.
The sulphur and peroxide vulcanizates contained 20, 30, 40, and 50 phr. of the filler were studied.
The article discusses also the test results of thermal stability and flammability of NBR 18 containing
silica prepared "in situ" from alkoxysilane precursor.
The test results were obtained with the use of derivatograph, measurements of flammability by the
method of oxygen index, and in air.
The effect of the silica modification on the SEM and AFM was also examined.
The method of cryogenic modification enables to achieve increase of mineral fillers activity towards
elastomer and reduction in the flammability of NBR 18 vulcanizates.
It has been found that the modification of the vulcanizates of NBR 18 with tetraethoxysilane that
makes it possible to form silica "in situ" reduces the flammability of cross-linked rubbers.
Authors:J. Ryba, A. Ujhelyiová, M. Krištofič, and I. Vassová
This article focuses on the thermal properties of PA 6 and additives, i.e. ternary copolyamides, concentrates consisting of
binary or ternary copolyamides + nanoadditive montmorillonite Bentonite 11958 or Cloisite 15A and PA 6 fibres modified with
Bentonite, copolyamide and concentrate. The copolyamides are prepared from ε-caprolactam as a major comonomer and nylon salts
AN2 from adipic acid + 1-(2-aminoethyl)piperazine and ADETA from adipic acid + diethylenetriamine. All copolyamides and concentrates
exhibit lower melting temperatures Tm and lower melting enthalpies ΔHm compared to neat PA 6. PA 6 fibres modified with 0.25–2.5 wt% MMT exhibit higher melting enthalpies in comparison with unmodified
PA 6 fibres. PA 6 fibres modified with 10 wt% of ternary copolyamide containing 21.4 wt% of comonomers AN2 and ADETA have
higher melting enthalpy as well. PA 6 fibres modified with 10 and 20 wt% of concentrate containing the same ternary copolyamide + 5
wt% of MMT have higher melting enthalpies and higher tensile strength in comparison with these characteristics of unmodified
PA 6 fibres.
Authors:D.-Y. Yang, Q.-X. Liu, X.-L. Xie, and F.-D. Zeng
The exfoliated poly(vinyl chloride) (PVC)/montmorillonite
(MMT) nanocomposites were synthesized by in situ intercalated polymerization
of vinyl chloride (VC) in the presence of organic-intercalated montmorillonite
(OMMT). Their structures and thermal properties were characterized. The results
showed that layered silicates are well exfoliated and uniformly distributed
in PVC matrix during in situ intercalated polymerization of VC in the presence
of OMMT. The glass transition temperatures of PVC phases in the PVC/MMT nanocomposites
are all lower than that of pristine PVC due to the incorporation of the exfoliated
silicate layers in PVC matrix. The 5% mass loss temperature (T5%),
the dehydrochlorination temperature (Tmax1)
of the PVC matrix decreased due to the free and interlayer water in MMT, the
low thermal stability, and the enhanced dehydrochlorination of the PVC matrix
by alkyl ammonium pre-treated MMT. However, the thermal decomposition temperature
of the dehydrochlorinated PVC (Tmax2)
and char at 600C are slightly increased in the presence of silicate layers.
The effect of carbon black with various particle sizes and specific surfaces on the thermal properties of the sulphur vulcanizates ofcis-1,4-polyisoprene was studied by means of thermal analysis. It was found that the addition of carbon black does not change the nature of the thermal processes in isoprene rubber vulcanizates essentially, but it distincly affects the positions of the peaks recorded in the DTA curves. The specific surface of carbon black affects the temperature of the first exothermic process and the temperature and rate of destruction of cross-linked polyisoprene. The presence of carbon black brings about a reduction in the flammability ofcis-1,4-polyisoprene vulcanizates. The specific surface of carbon black influences the value of the oxygen index OI.
The effect of mineral fillers such as Ultrasil VN-3, Ze−O−Sil P-45, Aerosil 200, Frantex 8, Kaolin and precipitated calcium
carbonate on the thermal properties sulphur vulcanizates ofcis-1,4-polyisoprene were studied by means of thermal analysis. It was found that the addition of a mineral filler did not change
the nature of the thermal processes in isoprene vulcanizates essentially, but it distinctly affected the positions of the
peaks recorded in the DTA curves. The mineral fillers affected the temperatures and rates of degradation and destruction of
polyisoprene cross-linked with sulphur. The presence of a mineral filler brought about a decrease in the flammability ofcis-1,4-polyisoprene sulphur vulcanizates.
DTA and TG methods were used to study the melting, polymorphic transformation and thermal decomposition processes of alkali metal and ammonium mixed bifluorides formed by mutual replacement of the cations in the crystal lattice. We studied the structural features and the characteristics in the changes of thermal properties of individual compounds, solid solutions with unlimited solubility and solid solutions with limited solubility.
Authors:Fu Shuren, Zhang Guanghua, Tan Qun, and Yang Yuqin
Thermal properties and morphology of crystal in NYLON 1010 formed isothermally at melting peak temperature were studied by
using DSC, TEM and ED. It turns out that the crystal on the time scale of the DSC experiment is stable, which is not transformed
from the crystal with low melting point. Its electron diffraction pattern shows symmetrical and clear electron diffraction
spots of single crystal and is proved to be the electron diffraction pattern of single crystal by means of index with parameters
of unit cell of Nylon 1010
Authors:S. Z. Haider, K. M. A. Malik, A. Rahman, and T. Wadsten
Six adducts of the tctrakis(8-hydroxyquinolinato) complex of thorium(IV) with 8-hydroxyquinoline, pyridine, urea, dimethylsulphoxide, dimethylformamide and 1,10-phenanthroline were prepared and characterized, the infrared bands for the room-temperature forms are given and their particular thermal properties are reported. The thermal analyses were performed mostly in the presence of air, but in some cases an argon atmosphere was used for comparison. The adducts were lost from the principal complex at temperatures varying between 110 and 290°. Intermediate oxygenated complexes were formed in each case at about 400°. The thermal data suggest the standardization of a procedure for the formation of Th(C9H6NO)4.