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boundary data reported by [ 5 ] and thermodynamic data. We then modeled the parameters of the intermetallic phases beginning with the congruent melting ( ). Finally, all the parameters of the different phases were simultaneously optimized with the
available in the literature. In the present parameter optimization procedure, we first imposed the conditions d 2 G /d x 2 for modeling the liquid phase ( 0 L Ru,Y ) using the phase boundary data reported by Massalski [ 6 ] and thermodynamic data determined
, Cesáro , A , Delben , F . Thermodynamic data for the water-hexamethylenetetramine system . J Phys Chem . 1971 ; 75 : 23 3633 – 3635 . 10.1021/j100692a027 . 6. Barone , G
, V , Cesàro , A , Delben , F 1971 Thermodynamic data for the water–hexamethylenetetramine system . J Phys Chem 75 : 3633 – 3635 10.1021/j100692a027 . 12. Speedding , FH , Pikal
1998 An internally consistent thermodynamic data set for phases of petrological interest Journal of Metamorphic Geology 16 309 343
_A1 structure (metastable) and Sn in bct_A5 (stable) structure was different in version 4.4. of the SGTE database in comparison with the value from [ 19 ], used by Fries et al. [ 8 ]. The phase diagram using the updated thermodynamic data for Al
Physicochemical properties of non-stoichiometric oxides
Mixed conductors: Part I
temperature thermodynamic data, , also provide information on the nature of the charge carriers as we discussed above. The charge carrier delocalisation suggested by the dependence of on “6+δ” data gives an additional insight for a charge carrier conduction
]: and from own results according to Eq. 16 was obtained: 17 i.e., E = 89.05 kJ mol −1 , ln A = 15.845 ( A in s −1 ). Thermodynamics Equation 9 is plotted on the basis of thermodynamic data for standard
. Fig. 4 Mass spectrum of [Co(PBT) 2 (Cl) 2 ]·8H 2 O complex Thermal analysis and thermodynamic data Thermal analysis curves (TG/DTG) of the PBT and their Mn
close to change of Δ H value of silver(I) mono-glycinate formation reaction ( Table 4 ). There is no unequivocal literature data about structure of complex compounds of silver(I) glycine-ion. In comparison with thermodynamic data it is possible
