Epoxy resins are very used thermoset polymers because of their good combination of high elastic modulus and mechanical strength and good chemical and thermal resistance. One of their main limitations, the low
Authors:Subrata Pradhan, Priyanka Brahmbhatt, Janardhanan Devaki Sudha, and Jisha Unnikrishnan
nonisothermal (dynamic). The basic assumption for the application of DSC technique to the cure of the thermoset polymers is that the rate of the kinetic process (dα/d t ) is proportional to measured heat flow. The cure kinetics of uncatalyzed thermosetting
Authors:Arunjunai Raj Mahendran, Günter Wuzella, Andreas Kandelbauer, and Nicolai Aust
and vitrification. Gelation is the incipient formation of a cross-linked network, and it is a most distinguishing characteristic of a thermo-set. Gelation does not usually inhibit the process of curing, and it cannot be detected by techniques which are
, thermo-set cure etc.
The conventional DSC has been extensively employed for studying the glass transition and crystallization. However, many metallic glasses have very small
]. Glass transition temperature ( T g ) is also a characteristic of each material, specially thermoset polymers. By definition, it is the temperature which defines when the polymer chains or network start their movements and it is the transition of a rigid