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Thermal properties of solid complexes with biologically important heterocyclic ligands
Part III. Thermal decomposition and infrared spectra of thiocyanato Mg(II) complexes with 2-hydroxypyridine, quinoline, and quinoxaline
studied thermal properties of many coordination compounds with heterocyclic ligands [ 1 , 2 ] since these compounds play an important role in many biological systems. The authors have studied the thermal behavior of Mg(II) complexes with pyridine and
The thermal properties of coordination compounds of the composition Cu(NCS)2L2 (whereL=pyridine, 2-, 3- and 4-picoline, and 2,3-, 2,4-, 2,5-, 2,6-, 3,4- and 3,5-lutidine) are dealt with. The thermal decomposition of these compounds begins with the release of the ligandL. The compounds with pyridine derivatives containing a methyl substituent at position 2 show a markedly decreased initial decomposition temperature. It was found that X-ray irradiation caused a reduction of the central atom Cu(II) in the coordination compounds under investigation. X-ray electron spectra data showed the stability of the compounds Cu(NCS)2L2 withL=picoline or lutidine having a methyl substituent at position 2 to be distinctly lower in the surface layers. From the given series, the compounds Cu(NCS)2(pyridine)2 and Cu(NCS)2(3,5-lutidine)2 exhibit an analogous course of thermal decomposition in nitrogen atmosphere up to 600°. The stoichiometries of thermal decomposition are discussed.
Thermal properties of solid complexes with biologically important heterocyclic ligands
Part IV. Thermal and spectral properties of 2-chloro- and 2-bromobenzoato Cu(II) complexes with nicotinamide and different bonded water molecules
.10.003 . 6. Lajdová , Ľ , Jóna , E , Šnircová , S , Miklovič , J , Segľa , P , Pajtášová , M , Ondrušová , D , Mojumdar , SC 2009 Thermal properties of solid complexes with biologically important heterocyclic ligands
The highly crosslinked dimethacrylic/divinylbenzene copolymers
Characterization and thermal studies
, characterization and thermal properties of highly crosslinked, hydrophilic stable spherical microspheres based on the new aromatic tetrafunctional methacrylate monomers and divinylbenzene (DVB) prepared by emulsion–suspension polymerization in the presence of pore
We describe an application of DSC as an analytical ‘fingerprinting’ method that has been used to characterize the thermal properties of wheat starch in low-moisture, wheat-flour-based baked products, including cookies, crackers, and pretzels. This use of DSC has enabled us to relate starch thermal properties, on the one hand, to starch structure, and on the other hand, to starch functionality, in terms of baking performance and finished-product quality.
.6988 . 21. Lopez , C , Briard-Bion , V , Camier , B , Gassi , J-Y 2006 Milk fat thermal properties and solid fat content in emmental cheese: a differential scanning calorimetry study . J Dairy Sci 89 : 2894 – 2910 10
Introduction Thermal properties of organic electrolytes in aqueous and non-aqueous solvents are of great importance for investigations of various kinds of interparticle interactions, solvophobic and structural effects, and
-3093(01)00920-6 . 14. Cheng X , Shi W . Synthesis and thermal properties of silicon-containing epoxy resin used for UV-curable flame-retardant coatings . J Therm Anal Calorim . 10.1007/s10973
The effects of low-density polyethylene or isotactic polypropylene on the thermal properties of ethylene-propylene-diene rubber were examined by using a rheometer and a derivatograph. Pronounced changes in the thermal properties of the rubber were observed as a result of the polyolefin addition.
The effect of mixed synthetic saturated acids and of cobalt salt of these acids on the thermal properties of peroxide vulcanizates ofcis-1,4-polybutadiene, Europrene cis, has been studied by derivatography.
