Authors:S. Tarulli, O. Quinzani, J. Dristas, and E. Baran
Complexes of Cu(II) with substituted o-acetoxy benzoic acids (5-haloaspirines, X-asp) with and without pyridine (py), of composition
[Cu2(X-asp)4] and [Cu(X-asp)2(py)2 ] have been synthesized and characterized. Electronic and vibrational spectroscopic data of these complexes are reported.
Its thermal behaviour was investigated by thermogravimetry and differential thermal analysis. In all complexes, the haloaspirinate
ligands decompose in two or three steps, starting with the break up of the coordinated acetoxy groups. CuO is obtained as
the final pyrolysis residue in all cases.
Authors:Amanda dos Santos, G. Chierice, A. Riga, K. Alexander, and Ellen Matthews
Eugenol is an allyl chain-substituted guaiacol in the biosynthesized phenylpropanoid compound class derived from Syzygium aromaticum L. and widely used in folk medicine. Nonetheless, its pharmacological use is limited by some problems, such as instability
when exposed to light and high temperature. In order to enhance stability, the eugenol molecule was structurally modified,
resulting in eugenyl acetate. The eugenyl acetate’s thermal behavior and crystal structure was then characterized by differential
scanning calorimetry (DSC) and X-ray diffraction (XRD) and compared to a commercial sample.
Authors:Kadri Siimer, Tiit Kaljuvee, Tõnis Pehk, and Ilmar Lasn
Thermal behaviour of industrial UF resins modified by low level of melamine was followed by TG-DTA technique on the labsysTM instrument Setaram together with the 13C NMR analysis of resin structure and testing boards in current production at Estonian particleboard factory Pärnu Plaaditehas
AS. DTA curve of UF resin which has been cocondensed during synthesis with even low level of melamine shows the shift of condensation
exotherm and water evaporation endotherm to considerable higher temperatures. The effect of melamine monomer introduced to
UF resin just before curing was compared. The effect of addition of urea as formaldehyde scavenger was studied.
Authors:V. Manríquez, C. Díaz, G. González, and I. Brito
Benzenesulfenamides with the formula R-S-N-(R′)2 (R=C6H5 andR′=NC4H8O, C7H7 and C6H11) and their chromium carbonyl complexes were studied by means of TG and mass spectrometric methods. The thermal behaviour of the compounds the stabilities of free sulfenamides are lower than those observed for the corresponding chromium carbonyl complexes. Combined thermogravimetry — mass spectrometry results suggest that the fragmentation mechanism of the carbonyl complexes involves cleavage of the Cr-S and Cr-CO bonds while that of sulfenamide depends mainly on the dissociation rates of the NR2 groups.
Thermal behaviour of blends based on N,N'-bis(4-itaconimidophenyl) ether (IE) and 4,4'-bis(4-allyl-2-methoxyphenoxy) benzophenone
(R1) or 4,4'-bis(2-allylphenoxy) benzophenone (R2) are described in this paper. The reactive diluent content was varied from 5-50% (mass/mass) in these blends. A decrease
in the melting point and exothermic peak temperature was observed with increasing mass percent of reactive diluent. Thermal
stability of blends was affected at high mass percentage of reactive diluents.
The Mössbauer spectra of Sm2Fe17Nx, prepared by the nitrogenation of Sm2Fe17 powders in an ammonia and hydrogen atmosphere, were observed at elevated temperatures to shed light on the thermal behavior
of nitrogen in the compounds Sm2Fe17Nx. It was found that there were large differences in thermal behavior between the starting Sm2Fe17, crystalline Sm2Fe17Nx (x≈1.7) and amorphous Sm2Fe17Nx(x∼7).
The thermal decomposition behavior of Sm2Fe17N3.2, developed as one of the most promising hard magnetic materials, was found to be different under different atmospheres.
Authors:Rodica Olar, Mihaela Badea, Dana Marinescu, and Ramona Mardale
derivatives, new complexes with such units incorporated in Schiff bases ligands have been synthesized and characterized. The complexes have been characterized by different analytical and spectral methods.
The thermalbehaviour of these derivatives was
Authors:L.-M. Zhang, W.-G. Xie, T.-T. Wen, and X. Zhao
The thermal behavior of five free anthraquinones (chrysophanol, emodin, physcion, aloe-emodin, and rhein) from rhubarb had
been investigated using TG, DTG and DTA technique. The results show that all the free anthraquinones have the similar TG and
DTG curve shapes, however, due to the substituted groups attached on the skeleton of 1,8-dihydroxy anthraquinone are different,
every anthraquinone has different mass loss features. Moreover, all the DTA curves of these free anthraquinones have two obviously
characteristic peaks, but with special curvilinear types, peak location and peak values. Therefore, thermal analysis (TA)
characteristics of anthraquinones above mentioned could be established, and it is possible to easily distinguish these anthraquinones
by using TA technique.
Authors:Mihaela Badea, Rodica Olar, Dana Marinescu, and Gina Vasile
A series of new complexes with mixed ligands of the type [ML(C3H3O2)2]·nH2O (((1)M=Mn, n=1; (2)M=Co(II), n=2; (3)M=Ni(II), n=4; (4)M=Cu(II), n=1.5; (5)M=Zn(II), n=0; L=3-amino-1,2,4-triazole and (C3H3O2)=acrylate anion) were synthesized and characterised by chemical analysis and IR data. In all complexes the 3-amino-1,2,4-triazole
acts as bridge while the acrylate acts as bidentate ligand except for complex (5) where it is found as unidentate. The thermal behaviour steps were investigated in nitrogen flow. The thermal transformations
are complex processes according to TG and DTG curves including dehydration, acrylate ion and 3-amino-1,2,4-triazole degradation
respectively. The final products of decomposition are the most stable metal oxides, except for complex (4) that leads to metallic copper.
Authors:X. Han, Y. Hu, Z. Lin, S. Li, F. Zhao, Z. Liu, J. Yi, L. Zhang, and X. Ren
Effects of fullerenes including FS, EFS and pure C60 on thermal behaviors of polyethylene glycol (PEG) have been studied by employing thermogravimetry-differential thermogravimetry
(TG-DTG), differential scanning calorimeter (DSC) and off-line furnace-type pyrolysis-gas chromatography/mass spectrometry
(Py-GC/MS). The products were collected by Cambridge filter pad which was widely used in analyzing the combustion products
of cigarette. The results showed that the addition of fullerenes obviously restrained the thermal decomposition of PEG. The
initial decomposition temperatures (IDT) and maximum decomposition peak temperatures (MDT) were evidently postponed by the
addition of fullerenes. Pyrolysis products with one or two hydroxyl end groups obviously increased with the addition of 10%
C60. The reasons of the changes were discussed from the aspects of reaction mechanisms.