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The oxidative degradation and C–C coupling reaction of dibenzoazepine derivatives by peroxydisulfate ion and sulfate radical in aqueous media

Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 107: Issue 1
DOI:
https://doi.org/10.1007/s11144-012-0463-z
Authors: Joanna Wiśniewska, Grzegorz Wrzeszcz, Stanisław Koter, and Tomasz Ligor

NMR data and assignments δ(ppm): C 1 = 149.3; C 2 = 133.2; C 3 = 132.1; C 4 = 129.8; C 5 = 129.4; C 6 = 124.4; C 7 = 120.4; C 8 = 58.02; C 9 = 55.11; C 10 = 55.07; C 11 = 48.72; C 12 = 48.67; C 13 = 46.52; C 14 = 21.16. IR data

Open access

The utilization of Ti-SBA-15 catalyst in the epoxidation of allylic alcohols

Reaction Kinetics, Mechanisms and Catalysis
Volume/Issue:
Volume 105: Issue 2
DOI:
https://doi.org/10.1007/s11144-011-0405-1
Authors: Agnieszka Wróblewska and Edyta Makuch

products of this process are: allyl-glycidyl ether, and 3-allyloxy-1,2-propanediol. These compounds are formed with selectivities of 5 mol% (20 °C)—13 mol% (60 °C). Bis(allyl) ether is formed with the selectivity 3–5 mol%, and acroleine with 1

Open access