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Abstract

The foliated low-grade metamorphic rocks of the Triassic Bagolyhegy Metarhyolite Formation, mainly of pyroclastic origin, host post-metamorphic quartz-albite veins containing abundant tourmaline and occasionally rutile/ilmenite. The study of the Ti-oxide-mineralized veins with SEM-EDX revealed an unusual mineral assemblage comprising fine-grained Nb–Ta-bearing oxides (columbite-tantalite series, fluorcalciomicrolite and other Nb–Ti–Y–Fe-REE-oxide minerals) intergrown with Nb-rich polymorphs of TiO2 (anatase, rutile), ilmenite and zircon enriched with hafnium. This high field strength elements (HFSE)-bearing paragenesis is unexpected in this lithology, and was not described from any formation in the Paleozoic-Mesozoic rock suite of the Bükk Mountains (NE Hungary) before. The host metavolcanics are significantly depleted in all HFSE compared to the typical concentrations in felsic volcanics and the mineralized quartz-albite veins have even lower Ti–Nb–Ta concentration than the host rock, so the mineralization does not mean any enrichment. From proximal outcrops of the Triassic Szentistvánhegy Metavolcanics, potassic metasomatized lenses with albite-quartz vein fillings containing rutile/ilmenite are known. We studied them for comparison, but they only contain REE mineralization (allanite-monazite-xenotime); the Nb–Ta-content of Ti-oxide minerals is undetectably low. LA-ICP-MS measurements for U–Pb dating of Hf-rich zircon of the Nb–Ta-rich mineral assemblage gave 71.5 ± 5.9 Ma as lower intercept age while dating of allanite of the REE mineralized quartz-albite veins gave 113 ± 11 Ma as lower intercept age. The REE-bearing vein fillings formed during a separate mineralization phase in the Early Cretaceous, while the Nb–Ta mineralization was formed by post-metamorphic alkaline fluids in the Late Cretaceous., controlled by fault zones and fractures.

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Abstract

The foliated low-grade metamorphic rocks of the Triassic Bagolyhegy Metarhyolite Formation, mainly of pyroclastic origin, host post-metamorphic quartz-albite veins containing abundant tourmaline and occasionally rutile/ilmenite. The study of the Ti-oxide-mineralized veins with SEM-EDX revealed an unusual mineral assemblage comprising fine-grained Nb–Ta-bearing oxides (columbite-tantalite series, fluorcalciomicrolite and other Nb–Ti–Y–Fe-REE-oxide minerals) intergrown with Nb-rich polymorphs of TiO2 (anatase, rutile), ilmenite and zircon enriched with hafnium. This high field strength elements (HFSE)-bearing paragenesis is unexpected in this lithology, and was not described from any formation in the Paleozoic-Mesozoic rock suite of the Bükk Mountains (NE Hungary) before. The host metavolcanics are significantly depleted in all HFSE compared to the typical concentrations in felsic volcanics and the mineralized quartz-albite veins have even lower Ti–Nb–Ta concentration than the host rock, so the mineralization does not mean any enrichment. From proximal outcrops of the Triassic Szentistvánhegy Metavolcanics, potassic metasomatized lenses with albite-quartz vein fillings containing rutile/ilmenite are known. We studied them for comparison, but they only contain REE mineralization (allanite-monazite-xenotime); the Nb–Ta-content of Ti-oxide minerals is undetectably low. LA-ICP-MS measurements for U–Pb dating of Hf-rich zircon of the Nb–Ta-rich mineral assemblage gave 71.5 ± 5.9 Ma as lower intercept age while dating of allanite of the REE mineralized quartz-albite veins gave 113 ± 11 Ma as lower intercept age. The REE-bearing vein fillings formed during a separate mineralization phase in the Early Cretaceous, while the Nb–Ta mineralization was formed by post-metamorphic alkaline fluids in the Late Cretaceous., controlled by fault zones and fractures.

Open access
Central European Geology
Authors: János Haas, Tamás Budai, István Dunkl, Éva Farics, Sándor Józsa, Szilvia Kövér, Annette E. Götz, Olga Piros, and Péter Szeitz

The 1,200-m-deep Budaörs-1 borehole provided important data for our understanding of the stratigraphy and tectonic setting of the southern part of the Buda Hills. Although previous reports contained valid observations and interpretations, a number of open questions remained. The importance of this borehole and the unsolved problems motivated us to revisit the archived core. The new studies confirmed the existing stratigraphic assignment for the upper dolomite unit (Budaörs Dolomite Formation) as the dasycladalean alga flora proved its late Anisian to Ladinian age assignment. An andesite dike was intersected within the Budaörs Dolomite. U–Pb age determination performed on zircon crystals revealed a Carnian age (~233 Ma), and settled the long-lasting dispute on the age of this dike, proving the existence of a Carnian volcanic activity in this area after the deposition of the Budaörs Dolomite. Palynostratigraphic studies provided evidence for a late Carnian to early Norian age of the upper part of the lower unit (Mátyáshegy Formation). This result verified an earlier assumption and reinforced the significance of the tectonic contact between the upper unit (Budaörs Formation) and the lower unit (Mátyáshegy Formation). Based on structural observations and construction of cross sections, two alternative models are presented for the structural style and kinematics of the contact zone between the Budaörs and Mátyáshegy Formations. Model A suggests a Cretaceous age for the juxtaposition, along an E–W striking sinistral transpressional fault. In contrast, model B postulates dextral transpression and an Eocene age for the deformation. The latter one is better supported by the scattered dip data; however, both scenarios are considered in this paper as possible models.

Open access
Central European Geology
Authors: Elemér Pál-Molnár, Luca Kiri, Réka Lukács, István Dunkl, Anikó Batki, Máté Szemerédi, Enikő Eszter Almási, Edina Sogrik, and Szabolcs Harangi

Abstract

The timing of Triassic magmatism of the Ditrău Alkaline Massif (Eastern Carpathians, Romania) is important for constraining the tectonic framework and emplacement context of this igneous suite during the closure of Paleotethys and coeval continental rifting, as well as formation of back-arc basins.

Our latest geochronological data refine the previously reported ages ranging between 237.4 ± 9.1 and 81.3 ± 3.1 Ma. New K/Ar and U–Pb age data combined with all recently (post-1990) published ages indicate a relatively short magmatic span (between 238.6 ± 8.9 Ma and 225.3 ± 2.7 Ma; adding that the most relevant U–Pb ages scatter around ∼230 Ma) of the Ditrău Alkaline Massif. The age data complemented by corresponding palinspastic reconstructions shed light on the paleogeographic environment wherein the investigated igneous suite was formed.

The magmatism of the Ditrău Alkaline Massif could be associated with an intra-plate, rift-related extensional tectonic setting at the southwestern margin of the East European Craton during the Middle–Late Triassic (Ladinian–Norian) period.

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