Authors:A. He, M. Ye, Z. Tang, S. Lu, Y. Gu, X. Fan, L. Zhao, and J. Gao
The recombination of hydrogen and oxygen in technical gaseous waste of nuclear power plants in enlarged scale experiment has
been studied on the basis of our previous work.1 The catalyst and its best operating conditions for recombination of hydrogen and oxygen determined in a small scale experiment
were demonstrated and tested. The results show that the data obtained in an enlarged scale experiment agreed well with that
of in a small scale test. The recombination rate of H2 and O2 was higher than 98.3% and 99.98% respectively. After recombination, the residual concentrations of H2 and O2 in waste gas were O2<3 ppm, H2<400 ppm. The Pd-Al2O3 catalyst and operating conditions determined for gaseous waste processing of nuclear power plants were satisfactory.
Authors:N. Wang, X. R. Zhang, D. S. Zhu, and J. W. Gao
Phase change materials (PCM) have been extensively scrutinized for their widely application in thermal energy storage (TES). Paraffin was considered to be one of the most prospective PCMs with perfect properties. However, lower thermal conductivity hinders the further application. In this letter, we experimentally investigate the thermal conductivity and energy storage of composites consisting of paraffin and micron-size graphite flakes (MSGFs). The results strongly suggested that the thermal conductivity enhances enormously with increasing the mass fraction of the MSGFs. The formation of heat flow network is the key factor for high thermal conductivity in this case. Meanwhile, compared to that of the thermal conductivity, the latent heat capacity, the melting temperature, and the freezing temperature of the composites present negligible change with increasing the concentration of the MSGFs. The paraffin-based composites have great potential for energy storage application with optimal fraction of the MSGFs.
Authors:J. Liu, Y. Hou, S. Gao, M. Ji, R. Hu, and Q. Shi
The eight solid complexes of zinc with L--methionine or L--histidine were prepared. The thermal decomposition processes of these complexes were determined by means of TG-DTG. The results show that their decomposition processes can be divided into three steps except for the complex Zn(Met)2 the decomposition of which is completed in one step. All the final products are ZnO.
Authors:M. Ji, J. Liu, S. Gao, B. Kang, R. Hu, and Q. Shi
The enthalpies of solution in water of RE(His)(NO3)3
H2O (RE=La—Nd, Sm—Lu, Y) were measured calorimetrically at 298.15 K, and the standard enthalpies of formation of RE(His)aq3+ (RE=La—Nd, Sm—Lu, Y) were calculated. The plot of the enthalpies of solution vs. the atomic numbers of the elements in the lanthanide series exhibits the tetrad effect.
Authors:J. Yi, F. Zhao, S. Xu, L. Zhang, X. Ren, H. Gao, and R. Hu
The decomposition reaction kinetics of the double-base (DB) propellant (No. TG0701) composed of the mixed ester of triethyleneglycol
dinitrate (TEGDN) and nitroglycerin (NG) and nitrocellulose (NC) with cerium(III) citrate (CIT-Ce) as a combustion catalyst
was investigated by high-pressure differential scanning calorimetry (PDSC) under flowing nitrogen gas conditions.
The results show that pressure (2 MPa) can decrease the peak temperature and increase the decomposition heat, and also can
change the mechanism function of the exothermal decomposition reaction of the DB gun propellant under 0.1 MPa; CIT-Ce can
decrease the apparent activation energy of the DB gun propellant by about 35 kJ mol−1 under low pressure, but it can not display the effect under high pressure; CIT-Ce can not change the decomposition reaction
mechanism function under a pressure.
Authors:J. Yao, Y. Liu, Z. Gao, P. Liu, M. Sun, S. Qu, and Z. Yu
A microcalorimetric technique based on the bacterial heat-output was explored to evaluate the effect of Mn(II) on Bacillus thuringiensis. The power-time curves of the growth metabolism of B. thuringiensis and the effect of Mn(II) on it were studied using an LKB-2277 BioActivity Monitor, ampoules method, at 28C. For evaluation
of the results, the maximum peak-heat output power (Pmax) in the growth phase, the growth rate constants (k), the log phase heat effects (Qlog ), and the total heat effect in 23 h (QT) for B. thuringiensis were determined. Manganese has been regarded as the essential biological trace element. Mn(II) of different concentration
have different effects on B. thuringiensis growth metabolism. High concentration (800-1600 μg mL-1) of Mn(II) can promote the growth of B. thuringiensis; low concentration (500-800 μg mL-1) can inhabit its growth.
Authors:Y. Y. Di, Z. C. Tan, L. W. Li, S. L. Gao, and L. X. Sun
Low-temperature heat capacities of a solid complex Zn(Val)SO4·H2O(s) were measured by a precision automated adiabatic calorimeter over the temperature range between 78 and 373 K. The initial dehydration temperature of the coordination compound was determined to be, TD=327.05 K, by analysis of the heat-capacity curve. The experimental values of molar heat capacities were fitted to a polynomial equation of heat capacities (Cp,m) with the reduced temperatures (x), [x=f (T)], by least square method. The polynomial fitted values of the molar heat capacities and fundamental thermodynamic functions of the complex relative to the standard reference temperature 298.15 K were given with the interval of 5 K.
Enthalpies of dissolution of the [ZnSO4·7H2O(s)+Val(s)] (ΔsolHm,l0) and the Zn(Val)SO4·H2O(s) (ΔsolHm,20) in 100.00 mL of 2 mol dm−3 HCl(aq) at T=298.15 K were determined to be, ΔsolHm,l0=(94.588±0.025) kJ mol−1 and ΔsolHm,20=–(46.118±0.055) kJ mol−1, by means of a homemade isoperibol solution–reaction calorimeter. The standard molar enthalpy of formation of the compound was determined as: ΔfHm0 (Zn(Val)SO4·H2O(s), 298.15 K)=–(1850.97±1.92) kJ mol−1, from the enthalpies of dissolution and other auxiliary thermodynamic data through a Hess thermochemical cycle. Furthermore, the reliability of the Hess thermochemical cycle was verified by comparing UV/Vis spectra and the refractive indexes of solution A (from dissolution of the [ZnSO4·7H2O(s)+Val(s)] mixture in 2 mol dm−3 hydrochloric acid) and solution A’ (from dissolution of the complex Zn(Val)SO4·H2O(s) in 2 mol dm−3 hydrochloric acid).
Soil moisture is a major driving force of plant community succession in restored meadows. Existing studies mainly focus on diversity-productivity relationships. However, studies which determine the effects of soil moisture on the plant community properties in restored meadows are lacking. In this study, we conducted a chronosequence analysis of the interactions between soil water content variation and plant community properties in meadows following passive restoration (3-, 5-, 9-, 14-, 17-, 21-year restoration) of abandoned farmlands on the Sanjiang Plain, China. Results showed that the plant community was characterized by ruderal plants in the initial year of succession, and then by perennial plants such as Calamagrostis angustifolia and Carex spp. in older restored meadows. Similarity of restored community to target site increased across succession time whereas species diversity gradually decreased. Plant height, coverage and biomass increased with restoration time, with plant density being the exception. The community height, coverage and root/shoot ratio were positively related to the water content in the surface soil layer (0–10 cm). Conversely, plant density was significantly and negatively related with soil moisture at 0–10 cm soil depth. Plant diversity (Shannon index, Richness index and evenness) was closely correlated to soil water content at the soil depth of 0–10 cm. Our findings indicate that vegetation of cultivated meadows could be effectively restored by passive restoration. Change of plant species diversity is an especially important response to hydrological recovery in restored meadows on the Sanjiang Plain.
Authors:A. He, M. Ye, Z. Tang, S. Lu, H. Cao, Y. Gu, X. Fan, L. Zhao, and J. Gao
The recombination of hydrogen and oxygen in technical gaseous waste of nuclear power plants has been studied. A highly efficient catalyst for reacting H2 with O2 to form water was prepared. Various operating conditions and factors affecting the recombination of H2 and O2 were tested and the best conditions were determined. Results show that the Pd–Al2O3 catalyst prepared had very good characteristics. The recombination rate of H2 and O2 was higher than 98.3% and 99.9%, respectively. After recombination, residual concentrations of H2 and O2 in waste gas were O2<3 ppm, H2<400 ppm. The Pd–Al2O3 catalyst and operating conditions determined for gaseous waste processing of nuclear power plants were satisfactory.
Authors:Y. Gao, Q. Sun, R. Wang, J. Feng, F. Lin, N. Cui, X. Chen, S. Xu, Y. Bai, and X. Xu
Stripe rust, caused by Puccinia striiformis Westend. f. sp. tritici Eriks., is a major disease that causes substantial losses to wheat production worldwide. The utilization of effective resistance genes in wheat cultivars is the preferred control of the disease. To study the inheritance of all-stage resistance in spring wheat cultivars Louise, WA008016, Express, Solano, Alturas and Zak from the Pacific Northwest (PNW) of the United States, the six cultivars were crossed with the Chinese susceptible variety Taichung 29. Single-spore isolates of CYR32 and CYR33, the predominant Chinese races of P. striiformis f. sp. tritici, were used to evaluate F1, F2 and BC1 generations for stripe rust resistance under controlled greenhouse conditions. Genetic analysis determined that Louise had one dominant resistance gene to CYR32, temporarily designated as YrLou. WA008016 had two dominant and one recessive resistance genes to CYR32, temporarily designated as YrWA1, YrWA2 and YrWA3, respectively. Express had a single recessive gene that conferred resistance to CYR32, temporarily designated as YrExp3. The two independent dominant genes in Solano conferring resistance to CYR32 were temporarily designated as YrSol1 and YrSol2. Alturas had two recessive genes for resistance to CYR32, temporarily designated as YrAlt1 and YrAlt2. Zak has one dominant gene for resistance to CYR33, temporarily designated as YrZak1. These six cultivars can be important resistance sources in Chinese wheat stripe rust resistance breeding.