The problem of converting measured intensities into mass concentrations arises from the fact that the measured intensity of a characteristic X-ray line of an element or compound depends not only on the mass concentration of that element or compound but also on the nature and abundance of the other constituents of the specimen. In this work the empirical coefficient method which comprises both absorption and enhancement effects of each element on each other element by parameters independent of mass concentrations was used for correction of enhancement effects from antimony and praseodymium on bromine in two groups of samples. The results of analysis of bromine shows a relative error of not more than ±4%.
A method is described for the simultaneous determination of cadmium, antimony and praseodymium by 14-MeV neutron activation analysis based on characteristic X-ray spectrometry. The results of analysis show a relative error not higher than ±5%, when diluted with H3BO3 /90%/ and utilizing the internal standard method to minimize the interelement effects.
14 MeV neutron activation followed by X-ray spectrometry was applied to the simultaneous nondestructive determination of cadmium, antimony and bromine, utilizing praseodymium as an internal standard. The results of analysis show a relative error not higher than ±5%, when the samples were diluted with H3BO3
-5% to minimize the interelement effects.
The intensity of characteristic X-rays emitted from one element may be reduced by partial absorption by other elements in the matrix, or alternatively it is enhanced by their presence. In this work the enhancement effect of antimony on bromine, cadmium and selenium are given. The dependence of the specific activity of each element /Cd, Br and Se/ on the ratio of the weight of Sb to that of the element is given, when the concentration of Sb is not very low /-5%/.
14 MeV neutron activation of ternary copper silver selenide gives rise to a predominant activity from the 0.511 MeV annihilation peak from the three elements when -ray spectrometry is used. To overcome the interference problems, X-ray spectrometry was applied to the simultaneous nondestructive determination of silver and selenium, after which copper can be determined by -ray spectrometry. The results of analysis show a relative error not higher than ±5%, when the samples were diluted with H3BO3 /90%/ to minimize the interelement effects.
The empirical coefficient method represents the absorption and enhancement effect of each element on each other by parameters independent of mass concentrations. This method is used together with the internal standard method for the determination of cadmium, bromine and selenium by 14 MeV neutron activation followed by X-ray spectrometry. The results of analysis show a relative error not more than ±5%.
An activation analytical method has been developed for determining Cd, Ag, Sb, Se, Br by 14 MeV neutron-induced X-ray emission spectroscopy using Pr as an internal standard. A good correlation was obtained between the activity ratio, RAo and the weight ratio, RW. Results are given after correction for self-absorption and without correction. The results are comparable in both cases when dilution with H3BO3 (90%) is applied. The elements listed can be determined at minor concentrations (0.01%) with a relative error not more than ±5%.
Loaded and unloaded polyurethane foams were examined as a preconcentration matrix in combination with neutron activation analysis.
The structure of the foamed polymer is not damaged by short irradiation periods. However the foam skeleton degraded after
irradiations for one hour or longer in a neutron flux of 3·1013 n ·cm−2·s−1. The presence of tin as a major impurity in the polyether-type foam has been detected. This may affect the sensitivity of
determination of the relatively short lived isotopes of the elements collected on the foam. On the other hand the polyester-type
foam was found to contain only very low amounts of tin. Antimony, indium, gold and mercury collected on the foams were determined
with reasonable accuracy.
Authors:E. Csányi, K. Bélafi-Bakó, N. Nemestóthy, and L. Gubicza
Ethanol recovery from aqueous fermentation broth by extraction using oleic acid with simultaneous esterification by lipase enzyme was studied. To determine the optimal conditions for the complex process, the ternary system was characterised; binodal curves and tie lines of (ethanol+oleic acid+water) system were determined. Enzymatic esterification of ethanol and oleic acid was carried out and resulted in higher than 50% conversion with simultaneous reduction of ethanol content in the broth. Finally, the effect of the ester product (ethyl oleate) on the distribution of ethanol was determined.
Authors:A. Barouni, L. Bakos, É. Zemplén-Papp, and G. Keömley
The possibility of using characteristic X-ray from radioactive products of reactor activation was investigated with particular emphasis on /n,/, /n,n/, /n,2n/, /n,p/ and /n,/ products with long half lives. The characteristic X-rays emitted are a result of electron capture or internal conversion processes during isomeric transition. First of all the sensitivity and detection limits were investigated.