Ammonium niobium oxalate was prepared and characterized by elemental analysis, XRD and FTIR spectroscopy analysis, which confirmed
that the molecular formula of the complex is NH4(NbO(C2O4)2(H2O)2)(H2O)3. Dynamic TG analysis under air was used to investigate the thermal decomposition process of synthetic ammonium niobium oxalate.
It shows that the thermal decomposition occurs in three stages and the corresponding apparent activation energies were calculated
with the Ozawa–Flynn–Wall and the Friedman methods. The most probable kinetic models of the first two steps decomposition
of the complex have been estimated by Coats–Redfern integral and the Achar–Bridly–Sharp differential methods.
Authors:Y. Qi, F. Xu, H. Ma, L. Sun, J. Zhang, and T. Jiang
Polyaniline/γ-Al2O3 (PANI/γ-Al2O3) composites were synthesized by in-situ polymerization at the presence of HCl as dopant by adding γ-Al2O3 nanoparticles into aniline solution. The composites were characterized by FTIR and XRD. The thermogravimetry (TG) and modulated
differential scanning calorimetry (MDSC) were used to study the thermal stability and glass transition temperature (Tg) of the composites, respectively.
The results of FTIR showed that γ-Al2O3 nanoparticles connected with the PANI chains and affected the absorption characteristics of the composite through the interaction
between PANI and nano-sized γ-Al2O3. And the results of XRD indicated that the peaks intensity of the PANI/γ-Al2O3 composite were weaker than that of the pure PANI. From TG and derivative thermogravimetry (DTG) curves, it was found that
the pure PANI and the PANI/γ-Al2O3 composites were all one step degradation. And the PANI/γ-Al2O3 composites were more thermal stable than the pure PANI. The MDSC curves showed that the nano-sized γ-Al2O3 heightened the glass transition temperature (Tg) of PANI.
Authors:C.L. Liu, X.Y. Wang, Z.M. Wang, S.S. Li, C.T. Xin, H.F. Wang, B. Li, and L. Jiang
The migration of 99Tc in a weak loess aquifer was investigated in-situ with undisturbed aquifer medium columns. The columns were obtained horizontally at a depth of 3236 m in an Underground Research Facility (URF). Quartz containing 3H (HTO) and 99Tc (in the form of 99TcO4-) was introduced into one end of the columns and the columns were covered tightly. Aquifer water was introduced into the columns directly from an experimental shaft in the UFR. Effluents from the columns were collected and the activity of 3H and 99Tc were determined with a liquid scintillation analyzer. The breakthrough curves of 3H and 99Tc indicate that 99Tc migrates a little faster than that 3H does in the aquifer.
Authors:M. Paul, A. Valenta, I. Ahmad, D. Berkovits, C. Bordeanu, S. Ghelberg, Y. Hashimoto, A. Hershkowitz, S. Jiang, T. Nakanishi, and K. Sakamoto
We report here a search for the “live” 244Pu in 1 kg deep-sea dry sediment collected in 1992 in the North Pacific. After a 546 day alpha-counting of a Pu fraction chemically
separated from the alkaline-fused sediment sample at Kanazawa University, AMS analysis was performed at Hebrew University
and Weizmann Institute. Only one count of 244Pu with no background ions was detected, indicating no excess over the expected stratospheric man-made fallout. A limit of
0.2 atoms of 244Pu cm−2·y−1 for extra terrestrial deposition was set under reasonable assumptions and it was then concluded from this result and the
available data on interstellar medium (ISM) that the abundance of 244Pu in the ISM is less than 2·10−11 g 244Pu (g·ISM)−1. Implications of the present result are discussed.