Authors:C. Colangelo, M. Huguet, M. Palacios, and A. Oliveira
The objective of the present work is the estimation of the210Po content in some beverages and in tobacco, in order to assess the corresponding collective doses to the population in Argentina. Yerba mate, tea leaves, their infusions and ground coffee were analyzed, as well as tobacco. Collective doses due to the annual consumption of the beverages described were found to be from 6 man.Sv to 1200 man.Sv. Results for210Po in tobacco ranged from 10 Bq·kg–1 to 80 Bq·kg–1. Lung doses due to the use of tobacco vary from 75 Sv·y–1 to 600 Sv·y–1.
Authors:Zhuang Guisun, Wang Yinson, Tan Mingguang, Zhi Min, and Pan Weiqing
Ten macro and trace elements were determined in the hair of GuiZhou and XinHuang mercury mine workers and children living near the mine by INAA and AFS. Comparative studies demonstrated that concentrations of certain elements were greater than those corresponding to the nonexposed population. The hair mercury contents of normal adults and children were 1.1 and 1.37 g g–1, respectively. Workers and children living in the polluted area show a mercury level range of 3.52–317 and 1.50–34.7 g g–1, respectively.
Authors:J. Phillips, F. Marcinowski, and K. Maconaughey
In an attempt to characterize radon distribution in residential settings, the USEPA initiated two distinct survey programs, the National Residential Radon Survey (NRRS) and the State/EPA Residential Radon Survey (SRRS). Each survey is different in their level of analysis, with the NRRS concentrating on a national sample, and the SRRS concentrating on individual statewide samples. Both surveys are random and statistically-valid, enabling the survey samples to be extrapolated to represent a much larger population. This paper details each survey's design and provides an examination of the unique approach each program uses to generate sound characterizations of radon distribution in the United States.
Authors:S. Hisamatsu, T. Katsumata, and Y. Takizawa
Tritium (3H) concentrations in diet samples from Akita City, northern Japan, and in human tissue samples from the general population of Akita Prefecture were analyzed to study fallout3H transfer.3H concentrations in human soft-tissue samples have been previously found to be similar to those in diet samples. In this study, higher organically-bound3H (OBT) concentrations were found in human costal cartilage and sternum samples than in the soft-tissues. Mean residence times of OBT in the cartilage and sternum were estimated to be 57 years and <6 years, respectively, with a single compartment model which took into account compartment growth.
Authors:J. Santos, C. Munita, M. Valério, C. Vergne, and P. Oliveira
Instrumental neutron activation analysis (INAA), have been used for the definition of compositional groups of potteries from
Justino site, Brazil, according to the chemical similarities of ceramic paste. The outliers were identified by means of robust
Mahalanobis distance. The temper effect in the ceramic paste was studied by means of modified Mahalanobis filter. The results
were interpreted by means of cluster, principal components, and discriminant analyses. This work provides contributions for
the reconstruction of the prehistory of baixo São Francisco region, and for the reconstitution of the Brazilian Northeast
ceramist population of general frame.
Authors:R. C. Eerlingen, H. Jacobs, H. Van Win, and J. A. Delcour
Gelatinisation temperatures as a function of moisture content were determined for potato starch. The native starch was then hydrothermally treated at a temperature 3% (Kelvin degrees) below the gelatinisation peak temperature and at moisture levels varying from 20 to 67% (by weight). Gelatinisation temperatures, temperature ranges and enthalpy values were affected for all treated samples. However, two sample populations could be distinguished: those samples treated under ‘limited’ moisture conditions and other samples treated in the presence of ‘extragranular’ moisture. A two-step hydrothermal treatment further increased the gelatinisation temperature, but the effect of the second step was small in comparison to that of the first.
This study aims to investigate whether known carcinogenic chemical elements in atmospheric deposition might be associated
with child mortality due to leukemia in the Portuguese population. A Bayesian hierarchical model was used to explore the association
between lichen biomonitoring measurements of four elements—As, Hg, Ni, Pb—and childhood leukemia death counts taken at small
administrative units. This geographical epidemiological study found a non-significant positive association between the risk
of childhood leukemia and levels of arsenic, mercury and lead, and a non-significant negative association between the disease
and the level of nickel. Lead seems to show a weaker association with childhood leukemia than arsenic and mercury.
As an example of the mapping of human hair composition, the territory of Uzbekistan was chosen. The data and the maps obtained were compared with the environmental situation and medical statistics. World maps were drawn on the basis of various authors' data. The possibility of using human hair for radioactivity studies is discussed on the basis of data obtained in the Chemobyl area. The proposed scheme of human hair analysis may be used for world mapping for chemical elements, radionuclides, pesticides, dioxines, PCBs, etc., either to picture the global situation or as a health status on the level of populations.
Authors:Sandra Babić, Alka Horvat, and Marija Kaštelan-Macan
A method for optimization of a TLC separation based on use of a genetic algorithm is described. The procedure was tested by optimization of the reversed-phase HPTLC separation of a mixture of six pesticides and satisfactory optimum results were obtained. The performance of the genetic algorithm was tested by measurement of the number of generations, the population size, the mutation probability, and the crossover probability. Three separation criteria (
**) were examined as fitness functions. The genetic algorithm was compared with the simplex method.
Authors:S. Hayami, T. Kawahara, Y. Maeda, K. Inoue, and O. Sato
Iron(III) spin-crossover complexes [Fe(pap)2]ClO4. H2O (1), [Fe(pap)2]BF4. H2O (2), [Fe(pap)2]PF6. CH3OH (3), [Fe(CH3-pap)2]ClO4. H2O (4), [Fe0.5Al0.5(pap)2]ClO4. CH3OH (5) and [Fe0.25Al0.75(pap)2] ClO4. CH3OH (6)were prepared andthe spin transition behaviors of the complexes have been studied from magnetic susceptibility and Mössbauer
spectroscopy measurements. The magnetic properties of light-induced metastable state are measured using Hg-Xe light source.
T1/2is temperature at which the populations of the high-spin and low-spin species are fifty-fifty. Metastable HS is produced by
light irradiation at 5 K. T(LIESST) is the temperature at which the populations of the metastable high-spin species decrease to one half and cooperativity
factor Cis defined as the parameter which presents the strength of cooperativity. The value of T(LIESST) decreases as T1/2increases and the plots of T(LIESST) vs. Cshow linear correlation. The effect of cooperativity of the complexes on the relaxations in solid was confirmed for the iron(III)