Authors:Kwang-Wook Kim, Eil-Hee Lee, In-Kyu Choi, Jae-Hyung Yoo, and Hyun-Soo Park
The electrochemical redox behavior of nitric acid was studied using a glassy carbon fiber column electrode system, and its reaction mechanism was suggested and confirmed in several ways. Electrochemical reactions in less than 2.0M nitric acid was not observed. However, in more than 2.0M nitric acid, the reduction of nitric acid to nitrous acid occurred and the reduction rate was slow so that the nitric acid solution had to be in contact with an electrode for a period of time long enough for an apparent reduction current of nitric acid to nitrous acid to be observed. The nitrous acid generated in more than 2.0M nitric acid was rapidly and easily reduced to nitric oxide by an autocatalytic reaction. Sulfamic acid was confirmed to be effective to destroy the nitrous acid. At least 0.05M sulfamic acid was necessary to scavenge the nitrous acid generated in 3.5M nitric acid.
Authors:I. Pitkänen, J. Huttunen, H. Halttunen, and R. Vesterinen
FTIR spectrometry combined with TG provides information regarding mass changes in a sample and permits qualitative identification
of the gases evolved during thermal degradation. Various fuels were studied: coal, peat, wood chips, bark, reed canary grass
and municipal solid waste. The gases evolved in a TG analyser were transferred to the FTIR via a heated teflon line. The spectra
and thermoanalytical curves indicated that the major gases evolved were carbon dioxide and water, while there were many minor
gases, e.g. carbon monoxide, methane, ethane, methanol, ethanol, formic acid, acetic acid and formaldehyde. Separate evolved
gas spectra also revealed the release of ammonia from biomasses and peat. Sulphur dioxide and nitric oxide were found in some
cases. The evolution of the minor gases and water parallelled the first step in the TG curve. Solid fuels dried at 100C mainly
lost water and a little ammonia.
Authors:Maria Marques, Cintia Matsumura, and H. Santo Neto
Brenman, J. E., Chao, D. S., Xia, H., Aldape, K., Bredt, D. S. (1995) Nitricoxide synthase complexed with dystrophin and absent from skeletal muscle sarcolemma in Duchenne muscular dystrophy.
Authors:Attila Szepes, Zsolt Dubravcsik, and László Madácsy
Madácsy, L., Velősy, B., Szepes, A., et al.: Effect of nitricoxide on gallbladder motility in patients with acalculous biliary pain: a cholescintigraphic study. Dig. Dis. Sci., 2002, 47 , 1975–1981.