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highest pressure studied, the saturation of the adsorbent is not reached. Furthermore, the adsorption of CO 2 is about twice as important as in methane ( Fig. 12 ). The differential enthalpies of adsorption are shown in Fig. 13 for CH 4 adsorption and

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. 2. Siriwardane , RV , Shen , MS , Fisher , EP , Poston , JA . Adsorption of CO 2 on molecular sieves and activated carbon . Energy Fuels . 2001 ; 15 : 279 – 284 . 10.1021/ef000241s

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, M 1996 Adsorption of CO2 on activated carbon: simultaneous determination of integral heat and isotherm of adsorption . J Chem Eng Data 41 : 1144 – 1148 10.1021/je960080f . 14. Berlier

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. The adsorption of CO 2 takes place at the adsorption sites on the carbon particle surface, probably as well as at the desorption vacancies left by the desorption of the product (CO) of interface reaction. The adsorption rate increased first to a

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. 2. Saha , D , Bao , ZB , Jia , F , Deng , SG 2010 Adsorption of CO 2 , CH 4 , N 2 O, and N 2 on MOF-5, MOF-177, and Zeolite 5A . Environ Sci Technol 44 : 1820 – 1826 10.1021/es9032309

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area by the BET equation ( S BET ), whereas the adsorption of CO 2 at 273 K was used to assess the narrowest micropores ( V DR (CO 2 )) (pore size smaller than around 0.7 nm) also by application of the Dubinin–Radushkevich equation at relative

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adsorption of CO 2 on a synthetic hydrotalcite . Chem Mater. 2006 ; 16 : 4135 – 43 http://dx.doi.org/10.1021/cm040060u . 36. Di Cosimo JI

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Reaction Kinetics, Mechanisms and Catalysis
Authors: Viorel Chihaia, Karl Sohlberg, Margarita Gabrovska, Rumeana Edreva-Kardjieva, Dorel Crişan, Peter Tzvetkov, Maya Shopska, and Iskra Shtereva

development of clean energy technologies . Catal Today 100 : 171 – 180 . 25. Yang , J-I , Kim , J-N 2006 Hydrotalcites for adsorption of CO 2 at high temperature . Korean J Chem Eng 23 : 77

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