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Abstract  

The extent of soil erosion in some Spanish semiarid regions has caused great concern regarding the sustainability of soil resources. Accelerated soil erosion, particularly in some Mediterranean areas, is likely to be one of the main environmental problems associated with climate change. Fallout 137Cs has been shown to provide a reliable basis for assessing soil erosion rates in different environments around the world. However, existing information concerning the spatial variation of 137Cs inventories at reference sites has identified a need for further investigation of the factors affecting their spatial variability in semiarid environments, where stony and skeletal soils are predominant. Reference sites at three locations in the central Ebro valley were selected to investigate the 137Cs content of several grain size fractions. Each site included both natural vegetated conditions and cultivated land and the three sites were characterized by different values of mean annual rainfall. The results obtained demonstrate the influence of lithology, land use and climate on the spatial variability of 137Cs inventories that increase from 1190, to 1500 and 1710 Bq·m−2 with increasing annual rainfall values from 300 to 500 mm at the study sites. The soils on marls at the Valareña site had the highest proportion of 137Cs in the coarse fractions of cultivated soils (12%) in comparison with soils developed on limestones at Loma Negra (5%), whereas no 137Cs content was found in the coarse fractions of soils on glacis-terrace materials at Peñaflor. The 137Cs reference inventories are higher in soils on marls and sands at cultivated locations at Valareña and Peñaflor, but have similar values in soils at cultivated and uncultivated locations on limestones at Loma Negra. Therefore, in absence of level undisturbed soils with natural vegetation cover, cultivated flat soils on hard rocks could provide reliable reference inventories.

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Acta Agronomica Hungarica
Authors: Z. Varga-Haszonits, E. Enzsölné Gerencsér, Z. Lantos, and Z. Varga

The temporal and spatial variability of soil moisture, evapotranspiration and water use were investigated for winter barley. Evaluations were carried out on a database containing meteorological and yield data from 15 stations. The spatial distribution of soil moisture, evapotranspiration and water use efficiency (WUE) was evaluated from 1951 to 2000 and the moisture conditions during the growth period of winter barley were investigated. The water supply was found to be favourable, since the average values of soil moisture remained above the lower limit of favourable water content throughout the growth period, except for September–December and May–June. The actual evapotranspiration tended to be close to the potential evapotranspiration, so the water supplies were favourable throughout the vegetation period. The calculated values of WUE showed an increasing trend from 1960 to 1990, but the lower level of agricultural inputs caused a decline after 1990. The average values of WUE varied between 0.87 and 1.09 g/kg in different counties, with higher values in the northern part of the Great Hungarian Plain. The potential yield of winter barley can be calculated from the maximum value of WUE. Except in the cooler northern and western parts of the country, the potential yield of winter barley, based on the water supply, could exceed 10 t/ha.

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agricultural production is a basic, traditional constituent of the Hungarian economy. An importance question nowadays is how the land can be cultivated and agricultural goods produced under the conditions of sustainable development. From the plant nutrition point of view the establishment of an environment-friendly fertilizer recommendation system is essential if sustainable development is to be achieved. Most experts agree that this type of fertilizer recommendation system is able to fulfil the growing demands of a growing population, while keeping the environment in good condition for the next generations. The experts also agree that fertilizer application could not be replaced widely with organic farming alone. An environmentally friendly fertilizer recommendation system has to be sensitive enough to respond to the effects of different conditions, e.g. great spatial variability of soil characteristics, mosaic-like soil cover, climate, crop rotation practices, soil nutrient supply, etc. There was a dramatic change in Hungarian agriculture at the beginning of the 90s, as the result of which the use of fertilizers decreased sharply for several reasons, e.g. privatization, changes in ownership, withdrawal of state subsidies for mineral fertilizers, drought, etc. Both Hungarian agriculture and the country as a whole is now facing two challenges, i.e. to overcome the economic difficulties and to complete the final phase of preparations to join the EU. Land use change scenarios have proved that the natural endowments of Hungary are suitable for integrating agricultural production with environmental and landscape protection and nature conservation.

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Abstract

Compound-specific isotope analysis (CSIA) is fast becoming an important tool to provide chemical evidence in a forensic investigation. Attempts to trace environmental oil spills were successful where isotopic values were particularly distinct. However, difficulties arise when a large dataset is analyzed and the isotopic differences between samples are subtle. Thus, this study intends to demonstrate any linkages between diesel fuels in a large number of datasets where subtlety in the isotopic values is accentuated by the near single-point source of origin. Diesel fuels were obtained from various locations in the South Island of New Zealand. Aliquots of these samples were diluted with n-pentane and subsequently analyzed with gas chromatography-isotope ratio mass spectrometry (GC-IRMS) for carbon and hydrogen isotope values. The data obtained were subjected to principal component analysis (PCA) and hierarchical clustering. A wide range of δ13C and δ2H values were determined for the ubiquitous alkane compounds (the greatest values being −4.5‰ and −40‰, respectively). Based on the isotopic character of the alkanes it is suggested that diesel fuels from different locations were distinguishable and that the key components in the differentiation are the δ2H values of the shorter chain-length alkanes. However, while the stable isotope measurements may provide information to classify a sample at a broad scale, much more detailed information is required on the temporal and spatial variability of diesel compositions. The subtle differences of the stable isotope values within the alkanes of different diesel fuels highlighted the power of CSIA as a means of differentiating petroleum products of different origins, even more so when two or more stable isotopes data are combined. This paper shows that CSIA when used in tandem with multivariate statistical methods can provide suitable tools for source apportionment of hydrocarbons by demonstrating a straightforward approach, thus eliminating lengthy analytical processes.

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A talaj N-szolgáltató képessége és az elérhető termés – többek között – függ a 0,01 M CaCl2-oldható szerves N-frakció mennyiségétől. Jelen tanulmányban vizsgáltuk, hogy a növényi kondíció és a termés hogyan változik a táblán belül egy heterogén növényállományban, és milyen összefüggésben van a 0,01 M CaCl2-oldható szerves N-frakció mennyiségével. Egy 10,4 hektáros mintaterületről növénymagasság térképet készítettünk, majd a különböző magasságú állományrészekben több ismétlésben mintavételi pontokat jelöltünk ki. Mintavételi pontonként termés- és talajmintákat vettünk. A mérési eredmények alapján megállapítottuk, hogy a termés, a levelek SPAD-értéke és a talajban lévő 0,01 M CaCl2-oldható szerves N-frakció mennyisége a növénymagasság növekedésével nőtt, míg a termésben jelentkező heterogenitás csökkent. Megállapítottuk, hogy a növényállomány heterogenitásában szerepet játszhat a 0,01 M CaCl2-oldható szerves N-frakció mennyiségének területi variabilitása is. A termés becsülhető a 0,01 M CaCl2-oldható szerves N-frakció mennyisége és a termés közötti összefüggést kifejező regressziós egyenletek alapján, viszont a becslés pontossága a különböző kondíciójú állományrészekben eltérő.

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. , Hou X. , Zha F. ( 2017 ), Seepage analysis of earth dams considering spatial variability of hydraulic parameters . Engineering Geology , 228 , 260 – 269 . [7] Wang

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respect to spatial variability of soil hydrophysical properties. Agrokémia és Talajtan, Vol. 51, No. 1–2., pp. 7–16. Rajkai K. Moisture regime with respect to spatial variability of

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. Proc. 39. 755–763. Farkas , Cs . & Rajkai , K., 2002.Moisture regime with respect to spatial variability of soil hydraulic properties. Agrokémia és Talajtan. 51. 7

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Agrokémia és Talajtan
Authors: Barbara Simon, E. Michéli, G. E. van Scoyoc, and et al.

The Typic Haplustalfs soils (Karád and Oltárc) and the Typic Ustochrepts (Gödöllő) are developed on loess, and on aeolian sand parent material, under forest vegetation, resp. The Dystric Ustochrepts (Velem) soil formed on metamorphic schist parent material and had forest vegetation, while the Typic Medisaprists (Zalavár) soil developed on peat parent material and had marsh vegetation.   Based on this study the spatial variability of surface pH samples indicate that the TIM sampling procedure should be improved. Ten to thirty samples must be collected at each site to be able to monitor changes of 0.2 pH units. If only one sample is taken at each site yearly, spatial difference in pH or other parameters are likely to obscure differences which may be occurring over time.  The colloidal composition (organic matter and clay minerals), influenced by parent material, vegetation, and precipitation, showed a close relationship with the acidity factors, such as pH, HAC 1 and EAC 1 values. The pH values were the lowest in the Velem and Oltárc soils where the annual precipitation was the highest (750-800 mm), and in the Karád soil, where the annual precipitation was 650-700 mm. The Gödöllő soil had the highest pH values, probably due to the lowest amount of rainfall (550-600 mm) and the disturbance. The Zalavár soil had fairly high pH throughout the profile probably due to a fluctuating water table.   The HAC 1 and EAC 1 values were the highest in the Velem soil when compared to the other mineral soils.  The pH values were the lowest at this site. The HAC 1 and EAC 1 values were lower in the other three forest soils, at the Karád, Oltárc, and Gödöllő sites. The Zalavár soil had fairly high HAC 1 values in the H3, H4 and H5 horizons, probably due to the very high OM content, which provided a lot of H + ions that can dissociate from the exchange sites.   The E4/E6 ratios were closely related to the decomposition or humification rate in the upper and the subsurface horizons with accumulation of low molecular weight soluble fraction in the deeper horizon.   The mineralogical analysis showed similar compositions for the soils developed on loess (Karád and Oltárc), or aeolian sand (Gödöllő), where the major minerals were vermiculite, mica, kaolinite, and chlorite. A different mineral composition (mica, vermiculite, clintonite, and kaolinite) was observed for the Velem site, where the parent material was metamorphic schist. The four mineral soils are forest soils, with a predominant downward water movement, thus with fairly intensive leaching process. However, there was a distinct difference among the soils formed on loess (Karád and Oltárc), or aeolian sand (Gödöllő), and the soil (Velem) developed on metamorphic schist parent material.  The soils at the Karád, Oltárc, and the Gödöllő sites were less acidified, with higher pH, and lower HAC 1 , and EAC 1 values as compared to the Velem soil, even if the precipitation was very high. The calcareous loess parent material probably compensated for the higher precipitation and the resulting leaching process at the Karád and the Oltárc sites. The Gödöllő soil received a very low amount of precipitation, which resulted in a low degree of weathering, with higher pH, and lower HAC 1 , and EAC 1 values. However, the metamorphic schist parent material probably contributed to a lower pH and lower buffering of the developing soil.   Based on the chemical and physical analyses, we concluded that among the soil forming factors, precipitation and parent material had the greatest influence on the acidity characteristics of the examined soils. The parent material influenced the mineralogy of the developing soil, which then influenced the pH, HAC 1 , EAC 1 , and CEC values of the soil. In order to substantiate these tendencies more samples from a wider array of geological regions are needed.   

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. BÁRDOSSY, GY. , 2006 . Geologic and geostatistical evaluation of spatial variability . Acta Geologica Hungarica . 49 . 89 – 101 . B OURENNANE

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