Search Results

You are looking at 61 - 70 of 142 items for :

  • "Installation" x
  • All content x
Clear All

Performance validation of step-isothermal calorimeters

Application of a test and reference reaction

Journal of Thermal Analysis and Calorimetry
Authors: B Finnin, M O'Neill, S Gaisford, A Beezer, J Hadgraft, and P Sears

Abstract  

Isothermal calorimetry is becoming indispensable as a tool for the study of a wide variety of systems. As with all scientific instruments it is essential that robust calibration routines be developed in order to validate the data obtained. Chemical test reactions offer many advantages over (the traditionally used) joule effect heating methods, not least because they have the potential to validate instrument performance (i.e. they can be used to assess all aspects of calorimeter operation). In this work the results of a validation exercise, conducted by Thermal Hazard Technology as part of an installation routine, using the base catalysed hydrolysis of methyl paraben are discussed. In the case described, a systematic misreporting of the reported temperature of a calorimeter was identified, caused by an upgrade to the calorimeter's firmware, a discrepancy which may not have been noted using traditional electrical calibration methods and one which highlights the importance of both manufacturers and end-users adopting chemical test reactions into their test and validation routines.

Restricted access

The present paper deals with the study of the installation behavior of high-strength bolts under friction. For this purpose an experimental program was conducted to evaluate the energy of these bolts that is dissipated due to tightening and loosening. The total number of tested specimens was 100 bolts furnished to the requirements of AASHTO specification M253M. The turn-of-nut tightening method is applied experimentally to evaluate the pretension and the torque for tightening and loosening of bolts. It is mentioned that a number of 56 bolts has 76 mm length while the rest is of 152 mm. The experimental preloading and the lost torque that overcomes friction are compared with the respective analytical values. It is confirmed that the K-nut factor is affected by the type of lubricant and the length of the bolt. Additionally, most of torque is going to overcome friction. The percentage of tightening and loosening torque for both the analytical and the experimental cases is very close.

Restricted access

In conjunction with its 30th anniversary in 2009 the Sóstó Museum Village examined the question of how to move forward. The best solution appears to be to take two directions: on the one hand, strengthening of the professional standard can bring renewal by transferring to the museum types of buildings or installations that have a curiosity value arousing the public’s interest (brandy distillery, soda-water plant, photographic studio, etc.), and on the other hand, strengthening our educational efforts, providing attractions for the public. We had thought that with the implementation of our building transfer plan the construction of the museum village could be regarded as completed, but we found that this was a mistake: there is no such thing as a completed museum, we are constantly faced with new challenges and we can only meet the expectations of the public by strengthening education and entertainment, expanding themes and complex services, and it is only in this way that we can provide a greater feeling of comfort for visitors. But in achieving this we must take care to avoid the danger of commercialisation and the “Disneyland“ effect. The article is about the attainment of this goal.

Restricted access

–100. Bastianini, F. – Rizzo, A. – Galati, N. – Deza, U. – Nanni, A.: Discontinuous Brillouin strain monitoring of small concrete bridges: Comparison between near-to-surface and „smart” FRP fiber installation techniques. Proceedings of SPIE – The International

Restricted access

] ČSN EN 15101-1 , Thermal insulation products for buildings – In-situ formed loose fill cellulose (LFCI) products – Part 1: Specification for the products before installation . [5

Open access

The present paper evaluates the results of field experiments conducted during two consecutive growth seasons (2008–2009) to assess the environmental impact of cement dust pollution on foliar physiology (pigments), growth performance and yield of three commonly cultivated vegetable crops, tomato (Lycopersicon esculentum), radish (Raphanus sativus) and knol-khol (Brassica oleracea var. gongyloides) in Kashmir Himalayan valley, India. Two experimental sites (S1, S2) were selected in the vicinity of the cement factory at Khrew, Pulwama (Kashmir) at a distance of 0.5 km (S1) and 2 km (S2) and compared with a dust free control site (S3) located at about 6 km from the factory in a crosswind direction. The data revealed that cement dust had an adverse effect on morphological and biochemical characteristics of the crops. Differential level of crop sensitivity to cement dust was markedly evident. Knol-khol (Brassica oleracea var. gongyloides) reflected a higher degree of tolerance to particulate emissions as compared to tomato (Lycopersicon esculentum) and radish (Raphanus sativus). Photosynthetic pigment analysis showed adverse impact on chlorophyll-a, while chlorophyll-b marginally decreased in the leaves of tomato plants at S1; the effect being non-significant for the other test crops. Carotenoids also exhibited a remarkable reduction due to cement dust impact. The yield of tomato recorded severe losses (12.28–23.95%) as compared to radish (7.46–21.4%), while the effect was non-significant in knol-khol. Other growth and yield related attributes also followed a similar trend; tomato and radish showing remarkable effects in response to cement dust and knol-khol showed the least effect. The soil characteristics indicated significant reduction in available P. Except available N, other variables (pH, conductivity, available K, exchangeable Ca and Mg) recorded higher values in the polluted soils as compared to control. The need for installation of appropriate devices in cement manufacturing factories to combat the emission of dust in ambient environment together with environmental monitoring of agro-ecosystems is stressed.

Restricted access

Abstract  

Lipiodol has excellent retainable ability in hepatoma cells. This agent can be labeled with radioisotope (131I) and mixed with tissue adhesive (Histoacryl), and then alttached on the lesion of liver by intrahepatic arterial administration. In this study, we attempt to obtain the optimal ratio of Lipiodol to Histoacryl and evaluate the consolidation of blood in vitro and toxicity and biodistribution in vivo. The ratio of131I Lipiodol/Histoacryl mixture (L/H), concentration of heparin and flow rate of blood are varied by simulating the installation of bloodstream to test the time of consolidation. In addition, the optimal ratios of the L/H mixtures are assessed in vitro in heparinized human blood. According to those results, Lipiodol and Histoacryl mixed with 1∶1 or 2∶1 ratio have an ideal time of 13 to 15 seconds in vitro; in addition, 1.2∶1 ratio is an optimal ratio in the biodistribution study. Interestingly, heparin and acetic acid does not alter the consolidation time, in addition, no variation occurs when varying the flow rate of blood. The consolidation of L/H mixture with blood is incubated in the 37°C, normal saline bath for 24 hours. No dissociation of free131I is found. The optimal mixture is also injected into the hepatic artery of the Sprague-Dawley rats carrying for 24 hours. No dissociation of free131I is found. The optimal mixture is also injected into the hepatic artery of the Sprague-Dawley rats carrying hepatocellular carcinoma (NIS1 cell line). Radioactive consolidate is well confined in the tumor without evidence of leakage of the mixture to the lung or distribution of free131I in the thyroid. In conclusion, this mixture has the merits of both irradiation and embolization of the tumor. The131I Lipiodol/Histoacryl mixture (1.2∶1) is a promising alternative for intrahepatic arterial administration to treat hepatic tumors. Histoacryl can confine the131I and, also, embolize the tumor vessels.

Restricted access

Abstract  

The Comprehensive Nuclear-Test-Ban Treaty (CTBT) plans the installation of an International Monitoring System (IMS) based upon four global networks. Seismic, hydroacoustic and infrasound waves will help detect underground, underwater and atmospheric nuclear tests and will permit their discrimination from natural events. 80 particulate stations will detect radioactive aerosols, this network being completed with a sub-set of 40 stations which will measure rare gases, typically xenon isotopes. 16 IMS laboratories will perform additional analysis mainly by gamma-spectrometry, using the most sensitive methods such as particulate analysis. In order to have the most effective network, modeling was performed by using an inverse method in which the radioactive tracer is transported back from detectors. Examples will be given, regarding the maps of detection probability, background effects of existing xenon or radon, or the decoupling effects. All these tools and means are anticipated to have a complete process of certification, authentication of the data and discrimination capabilities between nuclear test and releases from civilian nuclear industry (reactors, reprocessing plants,). If a State Party identifies events that it feels could be a nuclear explosion, it can ask for clarification and finally it may send a request for an On-Site Inspection. The rights of the State Party and the constraints for the Inspection Team are defined in the Treaty. That leads to limited time, to limited number of inspectors on the site and to precise methods to be authorized. The means and resulting data have to be blinded in order to make sure the confidentiality is observed. Examples of restricting measurements will be given regarding airborne or vehicle mounted spectrometry as well as laboratory analysis. Cooperation with international organizations (WMO, WHO) will be discussed, depending on confidentiality issues.

Restricted access

Abstract  

Release of long-lived radioactivity to the aquatic bodies from various nuclear fuel cycle related operations is of great environmental concern in view of their possible migration into biosphere. This migration is significantly influenced by various factors such as pH, complexing ions present in aquatic environment and sorption of species involving radionuclides on the sediments around the water bodies. 241/243Am are two major radionuclides which can contribute a great deal to radioactivity for several thousand years. In the present study, 241Am sorption on natural sediment collected from site near a nuclear installation in India, has been investigated under the varying conditions of pH (3–10) and ionic strength [I = 0.01–1 M (NaClO4)]. The sorption of Am increased with pH of the aqueous medium [10% (pH 2) to ~100% (pH 10)], which was explained in terms of the increased negative surface charge on the sediment particles. There was marginal variation in Am(III) sorption with increased ionic strength (within error limits) of the aqueous medium suggesting inner-sphere complexation/sorption process. Sediment was characterized for its elemental composition and structural phases using Energy Dispersive X-Ray (SEM-EDX) and X-Ray Diffraction (XRD) techniques. Zeta-potential measurement at I = 0.1 M (NaClO4) suggested that Point of Zero Charge (pHPZC) was ~2, indicating the presence of silica as major component in the sediment. Kurabtov plot using sorption data as a function of pH at fixed I = 0.1 M (NaClO4) indicated the presence of multiple Am(III) species present on the surface. Potentiometric titration of the suspension indicated the presence of mineral oxide like behavior and assuming a generic nature (≡XOH) for all types of surface sites, protonation–deprotonation constants and total number of sites have been obtained. The sorption data has been modeled using 2-pK Diffuse Double Layer Surface Complexation Model (DDL-SCM). ≡XOAm2+ has been identified as the main species responsible for the sorption profile.

Restricted access

A kutatás alapja az a feltételezés, hogy a paneles lakótelepek komplex megújítása városépítészeti léptéket követel, melyben az épületek földszintjei, a külső és belső térkapcsolatok újraértelmezése kiemelt fontosságú. A problémakör feltárása a hazai nagypaneles épületek földszintjeinek építészeti kialakítására épül. A cikk a rendelkezésre álló katalógusok alapján egyrészt a talajközeli térhatár (zárt, áttetsző vagy árkádos), másrészt a nyílások (bejárati ajtó, lakásablak, erkély, kapu, kirakat, közös tér ablaka, gépészeti nyílás, átjáró) tipológiáját állítja fel. Ezt a lakó és látogató számára fontos alsó szintet — a tömegterméket, a paneleket tartó, viszonylag sokféle, az adott helyhez is alkalmazkodó fundamentumot — nemcsak a panelházak építési korában, de az elmúlt évtizedek felújításai során is elhanyagolták. A műszaki vagy látványmegoldások alig érintik, így az épített környezetből a használatot terhelő problémák, mint például a rossz szubjektív biztonságérzet, a találkozások tereinek kerülése, az alulhasznosítottság stb. megmaradnak. Az írás a panelföldszintek építészeti megoldásainak összefoglalását adja, rávilágít az ezekből adódó használati problémákra, felhívja a figyelmet a témakör kiemelt kezelésének fontosságára.

Restricted access