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Journal of Radioanalytical and Nuclear Chemistry
Authors:
J. Chen
,
E. Hildebrandt
,
H. Delaney
,
W. Boivin
,
E. Bialas
,
E. Attas
, and
M. Heinrich

Abstract  

Automated alpha and gamma spectrometry systems have been fabricated to analyze large numbers of samples in batches and to perform on-line analysis for a number of experiments concurrently. Specially designed sample changers for alpha and gamma spectrometry and gamma scanners for used fuel and in-situ glass leach experiments have been built. These communicate through digital interfaces, microprocessors, microcomputers and programmable controllers to a Nuclear Data model ND6700 computer/spectrometer. Application software for data entry and reports has been written to interact with Nuclear Data software to pemit easy and efficient operation.

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Abstract  

Spent ion-exchange resins are produced in the purification of coolant and moderator systems during the normal operation of CANDU (Canada deuterium uranium) nuclear reactors. Carbon-14 is a radionuclide of concern in disposal of ion-exchange resins because of its relatively long half-life, its potential high mobility and its ability to be easily incorporated into organisms. Only limited data are presently available on the14C concentrations of spent from CANDU reactors. To establish a more comprehensive datahase for this radionuclide, concentrations of14C were determined for two moderator resins from Bruce Nuclear Generating Station A. Mixed bed resins were separated into anion and cation fractions using a sugar solution, and the14C concentrations were determined for each fraction. Carbon-14-was located predominantly on the anion beads. Samples of anion resin were found to undergo an 81% loss in the14C concentration over a period of 160 d following the sugar separation procedure. Some evidence is given to suggest this loss in14C may result from microbial activity. Concentrations and distributions of other predominant radionuclides, such as60Co and153Gd, are discussed as well.

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