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Journal of Thermal Analysis and Calorimetry
Authors:
A. Małecki
and
J. P. Doumerc
On the basis of previous modifications of the Zhuravlev and Ginstling-Brounshtein models, a generalization of kinetic diffusional models is proposed. With the assumption that the rate of the activation energy change during the reaction is inversely proportional to the reaction time, it has been shown that all diffusional kinetic equations in heterogeneous systems take the formF(α)=KT n , whereF(α) is a function of the degree of conversionα andK andn are constants related to the rate constant.
