Authors:Péter Sipos, Tibor Németh and Zoltán Máthé
The search for nuclear waste deposits have been focusing on formations containing large amounts of clay minerals, as they potentially possess significant isolation capacity due to their radionuclide sorption ability. In this study the immobilization processes for Co, Sr and Cs ions on the recently described analcime-containing rock type of the Boda Siltstone Formation were investigated by batch sorption experiments. Our data suggest a high radionuclide immobilization capacity for this rock formation in the following order: Sr > Co > Cs. The dominant immobilization processes were found to be ion exchange and precipitation for Co and Sr, and chemisorption for Cs. The necessity of further sorption analyses on the studied rock formation is also raised.
Authors:Andrea R. Varga, György Szakmány, Sándor Józsa and Zoltán Máthé
Upper Carboniferous (Westphalian) coal-bearing fluvial sediments (Téseny Sandstone Formation) of the Slavonian-Drava Unit and their reworked pebbles and cobbles occurring in the western part of the Mecsek Mountains in Miocene conglomerate sequences (Szászvár Formation) were studied. Based on the petrographic and geochemical characteristics, the sandstone studied consists of arkose, subarkose, litharenite and sublitharenite. The main clastic source was a recycled orogenic area (collision suture and fold-thrust belt) dominated by metamorphic rocks. It was associated with a probably Variscan magmatic arc as indicated by the volcanic rock fragments. The original source area of these clastic sediments was felsic and the analyzed sandstone could correspond to a continental arc/active margin tectonic suite. The pebble and cobble-sized clasts of the conglomerate were predominantly derived from acidic and intermediate volcanic rocks, low-grade regional metamorphic rocks (different types of schist, metasandstone, mylonite, metagranitoid, gneiss, quartzite, and metaquartzite) and siliceous sedimentary rocks. Among the sedimentary clasts, reworked black siltstone and fine-grained sandstone from older (possibly Carboniferous) deposits are common. Chert and contact metamorphic rocks are present in minor quantity. The extracted volcanic clasts consist of andesite, trachyandesite, dacite and rhyolite. Their geochemistry suggests convergent, active continental margin affinity. Upper Carboniferous siliciclastic successions are widely known at the southeastern margin of the European Variscides. In the area of the Upper Silesian Coal Basin, the Cracow Sandstone Series (Westphalian C and D) shows a similar petrographic composition to that of the Téseny Sandstone Formation. Additionally, volcanic clasts of the Upper Carboniferous conglomerate from southern Transdanubia and the calc-alkaline volcanites from the Intra-Sudetic Basin can be characterized by similar geochemical patterns.
Authors:Andrea R. Varga, György Szakmány, Béla Raucsik and Zoltán Máthé
In this paper, results of a bulk-rock geochemical study of silty and albitic claystone samples selected from the Upper Permian Boda Siltstone Formation (BSF) in the western part of the Mecsek Mountains (Tisza Mega-unit, Hungary) are presented. The high Na2O and P2O5 contents, relative to the post-Archean Australian average shale (PAAS) and the average Russian Paleozoic shale compositions, are the most striking features of the geochemistry of the Boda sediments. The samples studied are depleted in SiO2, TiO2 and Al2O3, and they are enriched in Fe2O3, MgO, CaO and K2O relative to the PAAS. The major element relations clearly show that the geochemistry of the BSF is strongly affected by post-depositional modification, corresponding to large-scale dispersal or addition of components. On the other hand, relatively high La content, low concentrations of V, Cr, Cu and Ni, and the result of the TiO2 versus Ni plot reflect a relatively felsic provenance of the BSF. By comparison with detrital mineralogy of the heteropic Cserdi alluvial fan system deposits, the authors assume that the Boda playa lake deposits had a similar immature primary composition consisting of quartz, plagioclase, K-feldspar, muscovite, biotite, chlorite and clay minerals. During weathering and transport in a semi-arid to arid climate, detrital mafic minerals were altered to yield chlorite and clay minerals plus Fe and Mg, and trace metals in solution. Mg was built into the structure of chlorite and of secondary carbonates such as dolomite and Mg-rich calcite. Based on previous geochemical studies, the BSF contains particularly sodic sedimentary rocks (up to 8 wt%) which may represent an addition of sodium in authigenic silicates from alkaline brine and/or evaporites in the playa deposits. In claystone, after albite formed, Na-depleted, Ca, K-enriched waters reacted with the clay minerals such as smectite and kaolinite to yield K-rich illitic sediments, Ca precipitated in calcite cement. P2O5 is enriched in some samples due to phosphorus mobilization during diagenesis.