The biologically active amines of grapes, aszú-grapes, aszú-wines of Tokaj region were analysed to study the effect of Botrytis cinerea on the grapes. It was established that grapes contained mainly spermidine, putrescine and spermine, however, in the aszú-grapes new amine compounds such as agmatine, phenethylamine, butylamine and pentylamine isomers appeared. The spermine content showed an increase in all aszú-grape varieties compared to the grapes. During winemaking processes, spermine disappeared and the concentration of tyramine increased in the aszú-wines. The concentration of spermidine decreased during the ageing of the product. The ratio of tyramine and amine content of the samples were found to be within a limited interval.