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  • Author or Editor: A. Spac x
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Abstract  

The paper deals with a kinetic study of crystal growth in gelatin and agar gels, using a technique based on radioactive tracers.204TlCl,204TlBr,204TlI,60CoC2O4 and60CoH4C4O6 crystals in gels have been obtained. The global kinetic process of appearance of crystals has been found to be made up of two distinct stages: diffusion of the ions in the gel and crystallization, having different rate constants.

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Abstract  

This paper presents a radiochemical study of the appearance of204T1I microcrystals and their development as disks resembling Liesegang rings, in gelatin, under different experimental conditions. Thus, kinetic diagrams have been traced, from which gel diffusion rate constants for radioactive ions were calculated, as well as reaction rate constants between reactant species:204T1+ and I, in colloidal medium, followed by the development of concentrated microcrystals under form of one or more disks. There is an interconnection between gelatin concentration of the colloidal medium, on one hand, and204T1I microcrystal disks number and dimensions, on the other hand, disks which appeared in gel as a result of the global process of nucleation.

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