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Abstract  

Experiments have been conducted to study the diffusion of iodide, cesium and strontium ions through intact and fractured rock samples of charnockite rock formation present at Kalpakkam, India. The diffusion coefficient (D i) of these ions for the intact and fractured rock samples has been evaluated and is found to be ranging from 0.76·10–14 to 6.25·10–14 m2/s and 0.67·10–9 to 84.6·10–9 m2/s, respectively. The study reveals that despite the sorbing nature of Cs and Sr, these ions diffuse comparatively faster than the iodide ion (non-sorbing) through the intact and fractured rock mass. The results have been validated vis-à-vis those reported in the literature and a good agreement has been noticed. This paper deals with details of the testing methodology developed to assess the radionuclide migration as well as the rock mass suitability for safe disposal of the radioactive waste.

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Abstract  

The extraction behavior of uranium (VI) from chloride medium with 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (PC-88A) in dodecane has been investigated under wide range of conditions. Attempts have been made to establish the extraction mechanism of uranium(VI) with PC-88A. Treatment of the distribution data by slope analysis technique showed the formation of a monomeric complex of the nature [UO2(A2H)2]. Formation of this species was also confirmed by non-linear least square regression of the distribution data to the mathematical expression correlating percentage extraction and acidity. In this investigation attempts have also been made to develop a mathematical model for the system (UO2Cl2-HCl-H2O-PC-88A-dodecane) using experimental data on the distribution of uranium against initial aqueous acidity at different initial metal concentration. The mathematical model D = 37.547±0.223/C i 1/2×[H i]2 can be used to predict the concentration of uranium in organic as well as in aqueous phases at any initial concentration of uranium [C i] and initial hydrogen ion concentration [H i]. The extraction constant (K ex) has been calculated.

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Abstract  

A new inorganic ion exchanger, zirconium hexacyanoferrate(III) prepared by adding potassium hexacyanoferrate(III) to zirconium oxychloride at 80°C has been found to be stable in acids and salt solutions. Distribution coefficient values determined for various metal ions show that the exchanger has a high affinity for bismuth. Binary separations of Bi(III) from a number of other metal ions at different concentrations were achieved on the column of the exchanger. Thus the exchanger has been found useful for the separation of bismuth from a large number of metals.

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Abstract  

α-Hemihydrate was allowed to hydrate in the presence of tartaric, succinic, malic or citric acids at room temperature at a water/ binder ratio of 0.35. Hydration of hemihydrate leading to the crystallisation of calcium sulphate dihydrate is an exothermic process. The temperature rise during hydration was measured as a function of time using a semi-adiabatic method. The temperature rise–time curves are similar for all investigated systems but with different induction period. The results showed that calcium sulphate dihydrate crystallisation is a nucleation controlled process and different acids are chemisorbed at the surface of forming nuclei to different extent. Processes taking place during nucleation may control the morphology of resultant crystals. Infrared spectral and differential scanning calorimetric studies confirmed the adsorption of carboxylic acids at the surface of dihydrate crystals.

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Some transition metal nitrate complexes with hexamethylenetetramine

Part LV. Preparation, X-ray crystallography and thermal decomposition

Journal of Thermal Analysis and Calorimetry
Authors: G. Singh, B. Baranwal, I. Kapoor, D. Kumar, C. Singh, and R. Fröhlich

Abstract  

Three hexamethylenetetramine (HMTA) metal nitrate complexes such as [M(H2O)4(H2O-HMTA)2](NO3)·4H2O (where M=Co, Ni and Zn) have been prepared and characterized by X-ray crystallography. Their thermal decomposition have been studied by using dynamic, isothermal thermogravimery (TG) and differential thermal analysis (DTA). Kinetics of thermal decomposition was undertaken by applying model-fitting as well as isoconversional methods. The possible pathways of thermolysis have also been proposed. Ignition delay measurements have been carried out to investigate the response of these complexes under condition of rapid heating.

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Polymerase chain reaction (PCR) was used to amplify the spacer regions between the 16S and 23S genes of rRNA genetic loci of Salmonella serovars for their rapid identification. These genetic loci revealed a significant level of polymorphism in length across the species/serovar lines. When the 16S-23S spacer region amplification products were subjected to agarose electrophoresis, the patterns observed could be used to distinguish all the serovars of Salmonella tested. Unique elements obtained in amplification products were mostly clustered at serovar level, although certain genus-specific patterns were also observed. On the basis of the results obtained, the amplification of 16S-23S ribosomal spacer region could suitably be used in a PCR-based identification method for Salmonella serovars.

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Abstract  

Solvent extractions of thorium(IV) and uranium(VI) by a commercially available chelating extractant LIX-26 (an alkylated 8-hydroxyquinoline) or 8-hydroxyquinoline, benzoic or salicylic acid, dipentyl sulphoxide (DPSO) and their mixtures with butanol as modifier in benzene/methylisobutyl ketone (MIBK) as the diluent have been studied. Extraction of uranium(VI) by 10% LIX-26 and 10% butanol in benzene becomes quantitative at pH 5.0. The pH 0.5 values for the extraction of thorium(IV) and uranium(VI) are 4.95 and 3.35, respectively. Quantitative extraction of thorium(IV) by the mixture of 0.1 M oxine and 0.1 M salicylic acid in methylisobutyl ketone was observed at pH 5.0. The influence of concentration of various anions on the extraction of Th4+ by mixtures of LIX-26 and benzoic acid has been studied. Studies on extraction of thorium(IV) and uranium(VI) by mixtures of LIX-26 (HQ) and DPSO show that the extracted species are possibly of the type [ThQ2/DPSO/2/SCN/2] and [UO2Q2/DPSO/], respectively.

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Abstract  

We describe a radioimmunoassay procedure for human somatotropin using second antibody — polyethylene glycol (PEG) combination for the separation of antibody bound and free antigen. The assay is done by a single incubation of 18 hours or with one hour pre-incubation and 3 hours post-incubation at room temperature (25 °C) and uses 0.1 m of serum sample. The assay covers a range of 0–40 g/ and has a sensitivity of 0.6 g/ of somatotropin. The assay is validated by inter-assay and intra-assay variations, recovery and parallelism tests.

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Abstract  

A radiochemical procedure has been developed for the simultaneous determinations of alpha-emitting isotopes of uranium and plutonium in bovine bone. The radiochemical recoveries ranged from 61 to 93% with a mean of 80±10% for uranium and 57 to 88% with a mean of 75±11% for plutonium. The method was successfully used for human bone.

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Double sulphates of uranium(IV) with Mg, Ni, Cu and Zn with the general formula MU(SO4)3·8H2O were prepared from their respective metal sulphates. All the four compounds are isostructural and belong to monoclinic system. The thermal decomposition at 850 °C results in a single phase of triuranates MU3O10 which on further heating above 980 °C decompose to give the metal oxide and U3O8 in case of Ni and Zn compounds and MUO4 for Mg and Cu compounds. The activation energy for dehydration of these four compounds has been calculated using non-isothermal thermogravimetric data.

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