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  • Author or Editor: Di Wang x
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Abstract

This study reports research on analyzing the impact of government funding on research output. 500,807 SCI papers published in 2009 in 10 countries are collected and analyzed. The results show that, in China, 70.34% of SCI papers are supported by some research funding, among which 89.57% are supported by National Natural Science Foundation of China (NSFC). Average grants per funding-supported paper in China is 2.95, when in the USA the number is 2.93 and in Japan it is 2.40. The results of funding agency analysis show that, China, Germany and Spain are single funding agency dominated countries, while USA, Japan, Canada and Australia are double funding agencies dominated countries, and the source of funding in UK, France and Italy is diversified.

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Abstract

In this paper, we use bibliometric methods and social network analysis to analyze the pattern of China–US scientific collaboration on individual level in nanotechnology. Results show that Chinese–American scientists have been playing an important role in China–US scientific collaboration. We find that China–US collaboration in nanotechnology mainly occurs between Chinese and Chinese–American scientists. In the co-authorship network, Chinese–American scientists tend to have higher betweenness centrality. Moreover, the series of polices implemented by the Chinese government to recruit oversea experts seems to contribute a lot to China–US scientific collaboration.

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Abstract  

The fate and transport of toxic metal ions and radionuclides in the environment is generally controlled by sorption reactions. The extent of sorption of divalent metal cations is controlled by a number of factors including cosorbing or complexing. In this work, the effects of pH, humic acid HA/Co(II) addition orders, ionic strength, concentration of HA, and foreign cations on the Co(II) sorption on γ-Al2O3 in the presence of HA were investigated. The sorption isotherms of Co(II) on γ-Al2O3 in the absence and presence HA were also studied and described by using S-type sorption model. The experimental results showed that the Co(II) sorption is strongly dependent on the pH values, concentration of HA, but independent of HA/Co(II) addition orders, ionic strength, and foreign cations in the presence of HA under our experimental conditions. The results also indicated that HA enhanced the Co(II) sorption at low pH, but reduced the Co(II) sorption at high pH. It was hypothesized that the significantly positive influence of HA at low pH on the Co(II) sorption on γ-Al2O3 was attributed to strong surface binding of HA on γ-Al2O3 and subsequently the formation of ternary surface complexes such as ≡S-OOC-R-(COO)xCo2−x. Chemi-complexation may be the main mechanism of the Co(II) sorption on γ-Al2O3 in the presence of HA.

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Abstract  

MX-80 bentonite is considered as one of the best backfill materials for high-level radioactive nuclear waste. Herein, the bentonite is characterized by using XRD and FTIR techniques. Sorption of radionickel to MX-80 bentonite in the presence/absence of humic acid (HA) or fulvic acid (FA) as a function of pH is investigated. The results indicate that the presence of HA or FA decreases the sorption of Ni2+ obviously. The different experimental processes do not affect the sorption of nickel to FA/HA bound bentonite. The sorption of Ni2+ on FA/HA-bound bentonite decreases with the increasing FA/HA content in the systems. The mechanism of nickel sorption is also discussed in detail.

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Abstract  

The complex (C11H18NO)2CuCl4(s) was synthesized. Chemical analysis, elemental analysis, and X-ray crystallography were used to characterize the structure and composition of the complex. Low-temperature heat-capacities of the compound were measured by an adiabatic calorimeter in the temperature range from 77 to 400 K. A phase transition of the compound took place in the region of 297–368 K. Experimental molar heat-capacities were fitted to two polynomial equations of heat-capacities as a function of the reduced temperature by least square method. The peak temperature, molar enthalpy, and entropy of phase transition of the compound were calculated to be T trs = 354.214 ± 0.298 K, Δtrs H m = 76.327 ± 0.328 kJ mol−1, and Δtrs S m = 51.340 ± 0.164 J K−1 mol−1.

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Authors: S. Wang, Z. Tan, Y. Di, F. Xu, M. Wang, L. Sun and T. Zhang

Abstract  

As one primary component of Vitamin B3, nicotinic acid [pyridine 3-carboxylic acid] was synthesized, and calorimetric study and thermal analysis for this compound were performed. The low-temperature heat capacity of nicotinic acid was measured with a precise automated adiabatic calorimeter over the temperature rang from 79 to 368 K. No thermal anomaly or phase transition was observed in this temperature range. A solid-to-solid transition at T trs=451.4 K, a solid-to-liquid transition at T fus=509.1 K and a thermal decomposition at T d=538.8 K were found through the DSC and TG-DTG techniques. The molar enthalpies of these transitions were determined to be Δtrs H m=0.81 kJ mol-1, Δfus H m=27.57 kJ mol-1 and Δd H m=62.38 kJ mol-1, respectively, by the integrals of the peak areas of the DSC curves.

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Abstract  

A laser-induced optical fiber fluorimetry has been reported for the analysis of ultralow level of uranium. The fluorescence spectrometer includes five major components: a pulsed nitrogen laser, optical fibers, an optrode, a detector, and a boxcar. The fluorescence intensity of uranyl ions is linear with respect to the concentration of uranium. The detection limit of uranium in 1M phosphoric acid is 24 ppb. This technique can be used for the remote, on-line measurement of low level uranium.

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Abstract  

Laser-induced optical fiber fluorimetry has been first used to analyze uranium(VI) concentration in the kinetic studies on the extraction of uranium(VI) between 0.5 mol/l H3PO4 solution and HDEHP-cyclohexane system with a Lewis cell. The effects of stirring speed, temperature and concentrations of uranium(VI) and HDEHP on the rate of extraction were examined. These data show that the extraction rate of uranium(VI) in this system is controlled by the chemical reaction at the interface. The rate equations and the rate constants of forward and reverse extraction are obtained. The mechanism of the extraction is discussed.

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Authors: Lu Li, Dan-Dan Xu, Jing-Xin Chai, Di Wang, Lin Li, Ling Zhang, Li Lu, Chee H. Ng, Gabor S. Ungvari, Song-Li Mei and Yu-Tao Xiang

Background and aims

Internet addiction disorder (IAD) is common in university students. A number of studies have examined the prevalence of IAD in Chinese university students, but the results have been inconsistent. This is a meta-analysis of the prevalence of IAD and its associated factors in Chinese university students.

Methods

Both English (PubMed, PsycINFO, and Embase) and Chinese (Wan Fang Database and Chinese National Knowledge Infrastructure) databases were systematically and independently searched from their inception until January 16, 2017.

Results

Altogether 70 studies covering 122,454 university students were included in the meta-analysis. Using the random-effects model, the pooled overall prevalence of IAD was 11.3% (95% CI: 10.1%–12.5%). When using the 8-item Young Diagnostic Questionnaire, the 10-item modified Young Diagnostic Questionnaire, the 20-item Internet Addiction Test, and the 26-item Chen Internet Addiction Scale, the pooled prevalence of IAD was 8.4% (95% CI: 6.7%–10.4%), 9.3% (95% CI: 7.6%–11.4%), 11.2% (95% CI: 8.8%–14.3%), and 14.0% (95% CI: 10.6%–18.4%), respectively. Subgroup analyses revealed that the pooled prevalence of IAD was significantly associated with the measurement instrument (Q = 9.41, p = .024). Male gender, higher grade, and urban abode were also significantly associated with IAD. The prevalence of IAD was also higher in eastern and central of China than in its northern and western regions (10.7% vs. 8.1%, Q = 4.90, p = .027).

Conclusions

IAD is common among Chinese university students. Appropriate strategies for the prevention and treatment of IAD in this population need greater attention.

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